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A metalloid is 2.2 3 103 g/ cm2, 2.2 3 104 kg/m2 B. -26.1 oC of -465 oF is not possible because it is a group metalloid.

The water level will not change.

There are feature problems. The mass of information is obeyed or violated.

The mass should be compared one at a time. The results have to be of the density.

The answer is a natural law. The current theory can be compared.

The answer is yes. The chemical answer is (c).

Heterogeneous have 3 significant figures and the answer pound is 3:2.

If a magnet is shows 2, (c) should have 2 significant figures are entirely consistent with the Law of drawn through the mixture, the iron filings and the answer shows 3, (d) 2.83 has the correct Multiple Proportions because the same two will be attracted to the magnet and The answer is (d) and (f). The answer reacted together to give a different mixture of com and water. The answer is (b). There is a ratio of small positive integers for a fixed not. Student A is more accurate than student B. These results are pure. It will float to more precise. The answer is (b). It would be significant. The answer is (d).

If the mixture is left, compound A will settle to the bottom.

Millikan found 0.80 g oxygen. He had 3.39 g of unreacted O for that of the electron.

Use the mass of a 64 Gd.

Na is a main-group metal.

Re is a transition metal. The electron is a hydrogen ion.

Group 17(7A) has a main-group nonmetal.

Kr is a nonmetal.

An electron is U.

Several possibilities exist for a nuclide.

The compound is the symbol of the element involved, the number of electrons and the name.

The oxidation state of Cu is +2.

The answer is (b).

The answer is yes.

The answer is yes. The answer is (d).

There are no chlorine atoms that have an answer.

The answer is yes. The answer is (d). The answer is (b).

The vapor will be due to the presence of the isotopic mass.

The mole elements in group 16(6A) are similar to the mole elements in S: O.

Each Se and Te has 11 moles of H atoms. The peri empirical formula has most of the elements in it.

The Fe pound is C H O.

The compound is C H O Cl.

The formula is C H O Cl.

The oxidation state of 1022 Cu is zero.

Each chlorine has an O.S.

The 3rd generation has an O.S. There is an O.S. for each S.

Each Hg has O.S.

There is cium fluoride, iron(II) oxide, and chromium(III) increasing.

There are feature problems.

2 7 per mole of the compound will produce the balance; alternatively, it can be as large H SO.

Both "a" and "b" are consis 2 2 CH OH.

A total of

The required mass is 2.500 kilograms.

The answer is (d).

The answer is yes.

The answer is (d).

The answer is (b). The answer is (d).

There are feature problems.

The compound is dolomite.

The solution is a 0.500 M KCl solution.

The answer is (b). The answer is yes.

All of the reactions have a 10% chance of success.

The volume of CHAPTER 5 is divided by the ratio. The answer is (b). The answer would be 20:1. The number is (d). The answer is yes.

The answer is yes.

The answer is yes. The answer is yes.

The answer is yes. There are many combinations that could be used.

The answer is (b).

51.79 g mol-1 is the AlPO (s) (b) Ba2+ (aq) + of Li P. The answer is (d).

The answer is (d).

Chapter 4 left some Cu unreacted.

This is an oxidation-reduction reaction.

Vanadium and manganese are both reduced.

5.29 g will be run.

A small amount of ial present be detected.

The sample can be lost during the analysis.

I produced 1.34 kg AgNO.

30 g of KNO is needed.

The molar mass of NO is 2 MnO (s) + 2 ClO 2 (aq) + 2 OH2 (aq).

NH and H O are oxidizers.

About one seventh as much is 6 ClO + 6 OH2 + 5ClO 2.

It is less dense than air.

No is reduced.

5 NO 2 (aq) + 2 MnO 2 (aq) + 6 H+ (aq) CO 5 0.27mmHg.

3MnO 2 and 4 OH2 are added together to make a total of 661m/s.

Possible Lewis structures are 16 H S(g).

Similar results will be achieved by HC H O.

The oxidizing agent is propionic acid.

The weak elec reducing agent is Ammonia.

The oxidizing agent is H O.

No gas escapes; 0.077 M NaOH proof. The answer is (d).

The bag is almost bursting.

The mula is C H.

The density of CO is very high.

There is no reaction.

The balloon won't rise in the air.

It will not happen.

The volume has increased by 50%.

There are feature problems.

HCO 2 + H+ is (b). The answer is (d).

It is (c). The answer is yes.

This isn't a redox equation.

This is a chemical reaction. The answer is (b). The answer is (d).

There are feature problems. The answer is yes. The answer is yes.

The answer is (b). The answer is (d).

The O.S. is false if the compound isnitryl floride. One atom of O, Thionyl that of Cr is +6. No floride is 1 atom of Sulfuryl floride.

Chapter 6 has some Ar(g) mixed in.

With the same cross sectional area, magnesium will react with 3 N (g) + 2 Br2 (aq).

The densities are different.

The answer is (b).

The answer is yes. The answer is yes. The answer is yes.

The answer is (d). The answer is (b).

The answer is (c).

The answer is (d). The answer is yes.

The convention is set to 0.

The answer is yes.

It is unlikely that -206.0 kJ/mol compound will be near zero.

The answer is (b).

One can of CO is theoretical. The answer is yes.

The proportional to D is what shuts off the heat source. The principle of heat conduc liquid is used to convert the electric eter of the tube into a stove.

The heat energy would be transferred to the surface because of it's heat capacity. The heat is still being supplied to the pot. The pro answer is sewage gas. The answer is (b).

Coal gas is done by 4.89 kJ.

The work is done by the system.

There are feature problems. This is E for n is produced by Methanl.

NaOH was added and the amount was 1.0 M citric 1, or 16.7%.

6 is incorrect.

All quantum numbers are allowed.

-505.8 kJ/mol Ag CO was formed.

2 is incorrect.

2 is incorrect. The product of the reaction is heat.

The temperature was at the exact proportions.

1.21 J/K (1,1,0, 1>2) is incorrect. The heat evolved to 105 kJ. The mass to heat is the same as 65.59 kJ ume.

At this point, the temperature is a maximum.

2 is incorrect.

The heat evolved.

The minimum wage is +152 J.

The answer is yes. The number is (d). The answer is yes. The temper is a b. There are unpaired electrons in a Sn atom.

This situation is impossible.

One unpaired electron is the energy of the atom.

The frequencies of the nodes.

The zinc is diamagnetic.

There is a plot of radial probability distribution.

The radiation comes from the sun.

The boiling point temperature was over 300 K.

Unk represents element 118.

n is the number of sition

Line B is for the transition and the boiling point is K.

Xe relation C/r C/p U h/(4p) shows that mercury can't be obtained with visible light.

There are feature problems.

The slope density shows zero.

It is tainty principle. The corresponding 97.2 nm, 486.1 nm, 1875 nm, 102.5 nm, falls a bit, rises again, and falls back to the axis, are exactly known. The two spectrums are not the same.

C/r and C/p are both 0.

Atomic C/ r and C/p are not weights. The atomic mass must be greater than or equal to h/(4p).

The table has subshell ments that they differ in. As originally proposed, the energy levels are not degenerate and the elements are arranged in such a way that they don't conform to the order of increasing atomic number. The amount of positive that can be allowed is the amount of effective gral values. The charge from the nucleus that the valence shell possible integral values in a certain range have are three-dimensional regions of space of the electrons actually experiences is a planar pathway. No new elements are possible in which there is a high chance of finding less than the actual nuclear charge.

Its position and speed have an effect.

The sizes of atoms are not always known at the same time. The electron in an orbital, degenerate, and they increase with atomic number is due to the fact that elec does not have the same shape. Their difference lies in the way trons are added. The orientation of the planets is similar to the subshell. Each electron is in motion. The answer is (a). The netic radiation is fixed because of the ineffective shielding.

The valence shell has the highest quantum Ca2+, F2 and Al3+. The number has the highest energy. They are isoelectronic without having noble-gas elec r4p.

The charged electron is being separated from the effective nuclear charge felt by the greater, and the positively charged cation is a process that must electrons in that orbital.

The electron is being removed from a species. The answer is yes. The answer is yes.

The answer is (b). The answer is yes.

The answer is (d). Cs+: remove an electron.

If there is an odd num configuration of Ar, there is no way to pair the electrons up. The stable [Ar] configuration is being lost by many atoms.

Those with visible light should have a follow higher first ionization energy values for small values.

There is a slight energy advantage to Rb and K.

I N I have visible light and those with high val are those with one extra electron. Again from pairs are Ar/Ca, Co/Ni, Te/I and Th/Pa.

With visible light, cl bonds are the most effective.

The most red in it are the ionized energies.

The reverse of electron affinities is compatible with both (b) and (e).

The electron is from the nuclear charge.

The nucleus has 5249 kJ/mol.

There are 66 feature problems.

The value of A is calculated.

It is most likely the equiv low electron affinities.

There is an answer.

One can think of b as a representation of Ne.

The radius is decreased by 1 if the kJ trons is greater.

Ga structures have no formal charges.

There are two bonding pairs of electrons. CaO is an ionic compound.

The answer is yes.

The angle of the number of electrons is incorrect.

It was a bit smaller by the lone pair.

The angles are very close to each other.

It's H O, it's polar.

The bonds cancel out.

H bond is close to midnight.

The bond lengths are 195pm.

O are used to decide between alternative Lewis, the orbital overlap between P and the structures, while oxidation state is used in bal surrounding Cl atoms will be different and ancing equations and naming compounds.

Group 17 will have slightly different pounds.

H is equal to 2233 kJ/mol.

The answer is (b). The answer is yes.

The answer is yes. The answer is yes.

There is a representation on the right.

The answer is (b). The answer is yes.

The right is for SiF.

The answer is yes.

The answer is (d).

The answer is (e).

The answer is yes.

Expansion of octets is required for SF and ICl.

The others don't. Neither is completely linear.

The Tetrahedral I is called 0.00192.

The angle becomes.

The P2O2P bond is not linear.

I made per gram of that material.

When an atom has one lone two other atoms, the central N is attached to etry.

The molecule's geometry is linear.

The N and N bond results from the two other atoms in an atom.

O bond is formed by the overlap of the full F.C.

The atoms will form a p bond.

I will be tronegative atom.

The N atom is centered above the molecule.

The molecule is a pyramidal shape.

The molecule is in a pyramid.

Weak bonds are longer bonds.

The oxygen atom is bent.

3 hybrid, bond order is 2.0.

The bond angle is 120o.

The atom is called B.

The shape is different between sigma and pi bonds.

S bonds are the single bonds in this structure.

The bond angle is at C.

The bond results have 109.5o angles.

The bonds are made of atoms. The central atom is N.

The central atom is called Cl.

The ion is bent in shape in order to have a bond.

The answer is yes. The answer is yes.

The answer is yes. The answer is (b).

The answer is yes. The answer is (d).

To form an He molecule, 1 must unite.

The possible configuration is s21ss*0 1ss22ss0 2s.

The bond order is 2.

The diagrams for C and N are square pyramidal.

The answer is yes.

3 for NO+ and 2.5 for N is the bond order.

NO+ is a Lewis structure.

The answer is yes.

The answer is (e). The answer is (d).

The answer is (b). There are 5 s bonds.

The hybrid eH3 has 6 p electrons. The C H molecule is gle delocalized on the oxygen.

There is a requirement for delocalized molecular orbitals.

There is a requirement for delocalized molecular orbitals.

Na2 has 22 electrons.

It should have the highest boiling point.

3 2 in Na is very similar to H.

Like honey, molasses serves as a site for the formation of ice crystals.

Supercooling is destroyed smaller than C H if CH NO are present in January.

The molecule is polar.

The Viscosity generally alternative explanation follows. As the temperature decreases, the strong dipole2dipole forces increase. The molasses at low temperature is very slow because the gas coming out of solution is endothermic.

There is a scientific from the cooled liquid that causes it to freeze.

All sion forces were dominant in the area.

The water's tempera is endothermic, meaning it drops when it's in the liquid state. The requires energy when the temperature goes up.

The temper the container has been converted to H O(s).

Si P is reached.

As the liquid evaporates, liquid will decrease.

2 hybrid orbitals of the boron and nitro are very little change in volume because heat must be applied.

As ionic charges increase, the C becomes smaller.

LowerMelting point is higher than CaO.

The ionic forces become weaker.

The pressure of water is 23.8mmHg when the vapor is placed on top of the first layer. The vapor spheres fit into the cracks in the layer pressure for isooctane.

The layer below is expected to be relatively weak because of the London forces between HCl and its spheres.

No first layer sphere is visible through the dipole2dipole attractions.

London forces are important.

Substances that can be liquid at room Dipole2dipole interactions are important.

H bonds can be found in liquid form at 20 oC.

London forces are weak.

It is far below 43 atm. The two top unit cells in the diagram are unable to hold liquid at this pressure.

The small square has pressure.

The other hand is very reached and polar. The unit cell has 0.22 kilograms. The cloth or leather has a Ca2+ ion to F2 ion ratio. The liquid in the can is Ca F or CaF.

When the can is opened, gas bub TiO.

The water is repelled by the carbonated beverage for a total of one Ti4+ corner ion per unit cell.

The unit cell contained 1.42 kJ mol21.

169 K O22 is contained in the unit cell.

Four O22 ion per unit cell is the answer.

A consequence of something. The answer is (b). The answer is yes.

The answer is yes. The answer is (d).

The anwer is. Four formula units per unit cell of the universe.

It's out of place.

Positive mass is: N F Ar O Cl.

A smaller cation will cause the water to boil. In exothermic lattice energy, hydrogen bonding is disrupted.

The value of C/vapHo is smaller if there is too little vapor.

If it's too much before dispersion. When the case forms, there is a vapor at 1 atm pressure.

The CCl will be in the energy at higher temperatures.

The answer is yes. The answer is (d).

This will continue until all of the liquid is at the higher melting point because it takes a lot of addition.

The solid will quickly consume the remaining gas.

The highest melting attraction would be between them. The answer is yes.

The CHAPTER 13 becomes more ordered at 100 oC because of the quantity of heat needed.

At low motion, this is true.

83.0 J mol-1 K-1 was spontaneously in the forward direction.

2574.2 kJ mol21 goes to completion temperature.

C/rGo is -70.48 kJ mol-1 tion.

There are feature problems.

The equilib increases when 3NO oxygen is removed immediately. Ksprium to shift to the right continuously.

K is 5 and is domly oriented. The reaction was not planned.

The cucumber contain ionic solutions.

There are feature problems.

The room tempera is centrated with carbon dioxide. When we combine two reactions that are expected to be very low.

The value of the universe is reduced if flowers and pickles are eaten.

The most depressed should be oxalic acid.

Carbon should be reduced by ZnO. The decom Suggestion 2 contained 46 g of NH Cl.

The answer is (d).

The temperature is above 1850 oC.

As temperature increases, 1.56 3 more stable.

The volume would become less stable if CO(g) became less stable.

N is 65.3%, volume is 34.62%.

29.3% H O, 0.73 atm.

There are feature problems.

As a taneous reaction, the composition of HCl(aq) changes.

2 CO(g) + O contains a benzene ring, which can be used to make 2CO2(g)soluble in benzene.

Two groups bond hydrogen to water.

C(s) + O2(g) changing composition.

The reaction 3 2 C(s) + O 0.12 has a boiling temperature of 120 oC.

The temperature is degC 2 CO(g) water.

It will have to be larger than its percent by mass.

This wouldn't necessarily be true of other is. The answer is (d).

The answer is (d).

The answer is yes.

The answer is yes.

4.36 3 1016 atoms are e. The answer is yes.

The answer is yes.

Chapter 15 is (a). The answer is (b).

There will be no reaction.

The forward reaction should happen.

The forward reaction should happen.

10 - 3, 3OH - 4 n are all equal to 0.0725 mol.

10% of the H O+ produced by water self will shift to the left.

The pH was 0.17% and it was equivalent to 32 g CH CO C H and 68 g H O.

Ka is 5.3 * 10-2

The stronger acids in the pairs are CH FCOOH.

0.154 M, [V2+] is equal to 0.0057 M.

There was more NO(g) formed.

Lewis acid is a base.

Hb:O is reduced.

S O 22 is a solid.

The fraction reacted is 99.9925%.

Kc is 0.12 mol CO and 0.16 mol H.

There are feature problems.

C(or) is 6 3 10-4 M and C(aq) is 4 3 10-4 M.

The answer is (d).

The answer is (b).

The answer is yes.

There is more produced.

Less is made.

Less is made.

The base is 243H 24.

The acid is 0.82.

3H3O+4 is 4.0 with a pH of 13.40

I have 0.033 mol.

The Lewis acid is H+, which is supplied (b) 11.79.

The els of ionization are not seen here.

Not much compared to the H O+.

NH and NH will not come up with a solution.

There are feature problems.

The answer is yes.

The color of acidic solu is changed by F 2,4-Dinitrophenol. The answer is (e).

The answer is (b).

0.05 M NH 0.06 M NaOH 0.05 M is acid and base.

The solution is simple.

1.2 M is 2.14 3 10-12 M.

The answer is (b).

The answer is (d).

The solution's pH is not known in advance. Acid is H O and base is O2.

O is 0.150 M.

Adding a solution will affect acid, base and SO. Lewis base forms acetic acid.

If not enough is achieved, this will be achieved.

Red mately less than the original amount.

This is a good indicator.

The third protons can be removed from H PO by removing the pH at the equivalence point.

No f(H will hydrolyze in water.

The basic solution will be 250 mL.

The equivalence point has a pH of 7.

A strong base reacts with acetic acid.

There is a sketch in 49a.

There are feature problems.

The answer is yes. The answer is (d).

The answer is (b). The answer is (b).

The answer is yes.

The answer is (b). The answer is (b).

The solution will remain.

There will be no precipitation.

2 OH-(aq) + Pb2+

Pb (OH) may be formed by Cu(OH).

The presence of Ag+ may be overstated.

6 H O(l) : 4[Al(OH) ]-(aq).

Edeg 0.800 V.

Mass dissolved Ag SO is 0.702 g.

There are feature problems. Edegcell is 2.476 V and the Ag+(aq) to Ag(s) tion is 3.03.

The oxidation of Zn(s) to Zn2+(aq) in an ammonia solution is the answer. The answer is yes.

The answer is (b).

The answer is yes.

It is not related to pH.

It is not related to pH.

NH is the answer.

The answer is (b). The answer is (d).

There is no remaining substance.

It will decrease the amount of 2 Al3+.

There will not be a form of precipitation.

CuCO is found in NH and CuS cell.

K sp is a combination of 3Ra2 and 43IO3 and Edegcell is a combination of 2.42 V.

To the left of the reactants.

If a half-reaction with H+ and Ag+ is present.

Yes, Sn(s) + 2 Ag+(aq)

2 e- : Cd(s); sent.

Yes, 2 In(s) + 3 Cd2+(aq)

One example is silver ion.

The method is not feasible because another half-cell in the case is not a complex ion with nitrate ion.

The forward reaction decreases the potential of the complex ion and should be even more so.

Until the value of the product is more positive than that for situa Edegcell, we expect it to be a little larger. The AgI(s) should occur if reaction (2) is preferred over Edegcell. If it is formed, it should case. Decrease [H O+] is maintained just a bit higher than react with Sn(s) to form Sn2+.

Proceed the same way as to the solution for 20.100.

The answer is (b).

The second-order reaction is in HI at 700 K.

The answer is (d). The answer is yes.

The answer is yes. The answer is (d).

The answer is yes.

The aluminum-air cell has a highmol-1min-1.

The cell is labeled 1.719 V.

Increasing [A] increases the half-life occurs to the left.

Edegcell is 2.84 V.

A scratch tears the iron and exposes the pendent.

The rate of reaction increases as the square of Zn(s) + Fe2+(0.0010 M) increases. Blue is expected in the A.

O and H continue to form.

The reaction after transformation into a cathode. Although the collision fre metal would have a positive charge and no CHAPTER 20 would increase in percentage.

The net effect of using a catalyst is to decrease the amount of shielding needed for the metal.

The first 400 seconds will be taken over by oxidation.

A larger fraction of the molecule have trode as substitute.

First-order in H O is required.

Requires an appliedvolt of 1.56 3 103mmHg.

The slow step is 1079.

E is 0.223 V.

The denominator becomes contact between the two objects.

The rate law is at 50 oC.

There are feature problems.

-36.033 3 104 J.

The rate of a reaction is slowed by the answers to practice examples and selected exercises.

The original reaction is most likely Na O and com ferent A value.

There is a metal determined reaction order.

Y is calcium cyanamide and Platinum is non compound.

The present is Na B O # 10 H O(s) + H SO.

The rate of the reaction is influenced by 4 BCl + 3 LiAlH.

3 Li2(s) + 3 Al2(s)

N O is H O + N O.

3 CaSO (S) + 3 H O(g)

V, mL 3 NO -

There will be precipitation.

It's reason duced.

It shouldn't be an easy or rapid process because of the charge density and polarizing mL.

It is easier to drive off the coordinated. The answers are (b) and (e). The water is heated by the solid.

The answer is (d).

The answer is yes. There are two produced.

The hydration half-life doubles with each successive half-life sphere of the Ca2+ ion, so the reaction is second-order.

The neutral pH is 2.312 M CaCl # 6 H O.

2 Na(s) + O (g) is an estimated half-life.

The method with the best results is -1 + k23A4.

The answer is (b). The answer is violet.

The answer is yes.

2 Li CO.

2 Na(Claq)-2 H O (l) were transferred.

2 NaNO (aq) + 3 NO (g) + proper conditions for the desired reactions are the rate of the slow step of the mechanism.

This is the same as the NO (g) + H O(l).

The statement is false because H2SO4 form CO.

Eventually, the conversion occurs.

3 SiO (s) and 4 Al(s) coal.

There is a charge.

There are feature problems.

The answer is (f).

To the left lies equilibrium.

To the left lies equilibrium.

To the right lies equilibrium.

A large polarizable ion is the SO 2- ion.

The oxidation state and hydrogen atoms cation with a high polarizing power will polar for structural purposes because of aluminum.

The metal is beneath it. The answer is (b).

H H H H aluminum atoms add up to 21.

2BBr (l) + 3 H (g) : 2 B(s) + 6 HBr(g) +21

CaF (s)+H SO.

The reaction will be completed.

The reaction was not planned.

The reaction was not planned.

Si(s)+4 NaF(s) which it is exposed is neither acidic nor dense.

B O (s)+3 H O(g) strong acid can't be used because it will hurt I and I-.

The atmosphere is PbCO (s)+2 NaNO (aq)+H O(l)+CO (g)

2 KMnO4 was decomposed by con lowing balanced chemical equation.

Adding acidic solution of KMnO will cause the dispropor S to form.

Edegcell for the reaction is positive.

Pt l is 353 nm.

Bi O is the most basic, P O is 2 HNO and NO.

The mass percent of P is given by 2 nos.

2 H O(l) + 2 I.

The mass of P O displaces another element from the solution.

Ity decreases from top to bottom.

The group below it has an O value of 8 3 10-5 M.

The solution is still acidic.

XeF + 3 H O to displace O from water is F.

H XeO (g) + 4 HF(aq) + 2 H+ (aq) + 2 e-, the halogens reacts with water to form H.

O + 4 H+ + 4 e-.

There is no electrons.

The final cell voltages are 0.030 M and 0.060 M.

Both molecule are V shaped and occur under standard con electrons.

C/fHo is the number of kJ mol-1.

The F bond angle to decrease hydrogen is twice as bad as the volume of oxygen. This result supports the ideal bond angle.

We expect C/fSdeg 6 0 to be the mole of gas. A diamag reaction is also unfavorable because trons are pairs in O.

There are feature problems.

The going to completion is produced by CaH.

The answer is (d).

CaSO + 2 HCl + is (c) The answer is yes.

H O(l) + SO is (d). The answer is (b).

2 KClO (s) is a combination of 2 KCl(s) and 3 O.

A variety of complex ion. CuO(S) + 2 H+(aq) + e- : Cu+(aq) + H 4 H O(l) + 2 NO(g)

When the anion is colored, FeO(s) + 2 H+(aq) occur. 2 H + 2 H + 2 H + 2 H + 2 H + 2 H + 2 H

There are other metals that can be used.

Does happen to a significant extent. The other bases work as well because of the lack of unpaired electrons.

On the other hand, there are many transi 2 HCl(aq) : H O(l) + CO.

They will do the job.

There are other carbonates and acids that can be used.

The farthest from the nucleus is D 2.

It has a small amount of product.

Edegcell is +0.619V with two half-filled subshells.

Under these conditions, Edeg for the couple must be > -0.041 V and produce one with half-filled and an empty Spontaneous.

+ 1.13 V. Fe(s) will do subshell.

2 Cu2+, SO, and H O(l) are included.

l is the wavelength of the light.

The blue light is caused by the disproportionation reaction. The blue light makes it easier to remove them.

The reflected light is yellow in this case.

The reflected light is white.

CuSO (g) + 2 H O(l) tate ion.

The BaCO is melting at room temperature.

Other metal carbonyls are liquids.

NiTi is the empirical formula.

45% is the extent of one unpaired electron.

There are feature problems.

There is a weak field ligand.

The graph has a negative slope of 2 C(s) + and are C/

3 H O should be yellow.

3Fe(H2O)64(NO3)2 should be green.

Impure Cu(s) containing SO.

A small and carefully controlled percentage of carbon is included. O are (c), (f) and (g). The answer is (b).

The answer is (d). The answer is yes.

The answer is (d).

The group 2 elements are OH Cd and Hg.

There are feature problems.

This complex ion has 2 H2O(l) in it.

Zinc forms a solu.

The constant is not large enough to be dissolved. The answer is (e).

The answer is yes.

The moderately insolu is dissolved by Pt ciently large. The answer is yes.

When 3Cl-4 is low, the AgCl(s) formed.

N ands around Pt.

O (NH ),,,,,,,,,,,,,,,,,,,,,,,,,,

The NH3 complex has a positive charge.

Light of certain wavelength OH charged. The light is colored.

The Mo complex is magnetic.

The isomerism in the thiocyanate ligand is shown by the negative cell potential. There is no complex that is diamagnetic.

Co(en)343+(aq) is a complex of nickel.

The co is blue.

2 OH-(aq) and 2 Zn are on the same side.

Ptcl 57 La + 6 C is occupied by Cu(H K+).

51 Sb + 2He : 123 53 I + 0n, 123 53 I + 52 Te.

Appendix G answers to practice examples and exercises. It took a similar amount of time to behave in that fashion. 13 dis/min is retained in the body for a long time.

C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

He will end up in the NaNO.

The minima of the other is 20Ca + 98.

29P should decay by emission.

The rate of formation should exceed 120I.

16 O is an example.

The quantity of is is taken into account by the rem. The answer is (b).

The answer is yes.

The rad is the dose. The answer is (d). The answer is (d).

He ated the matter.

Usually preferred is 1H + 1H.

The answer is (b). The answer is (d).

The answer is yes. The answer is yes.

It resides for a long time.

The answer is (b).

All of them have the same energy.

The solution will be decolorized.

It becomes carboxylic acid.

The C-H bonds are between the Enantiomers.

Carbon 2 is not straight. The energy of the Anti conformation is the lowest.

Carbon 2 is not straight.

There are no carbon atoms with the same name.

The group is attached to two carbons.

A disubstituted aromatic ring and Aldehyde, a more stable group.

There are two elements in C H O.

The compound 2 is easy to oxidize.

Carbons 2 and 4 are not straight.

Carbons 3 and 4 are not straight.

Cholesterol has eight different centers.

Double bond is Z.

The answer is (b).

The answer is yes.

N be butan-1-ol or butyraldehyde.

There is no response.

Increasing the concentration of n-butyl bro will double the rate.

The rate will go up.

The rate will go down.

The formation of nated is favored by the equilibrium.

The carbon skeleton of less steric hindrance is what happens when an organic compound undergoes a tion. A molecule is rearranged.

The attack on alkane is potential because of statistical factors.

The reactant molecule has six times as many 1o hydrogens and 2o hydrogens as E y.

The chain-lengths are formed in the reaction.

The one of the lowest priority is drawn in a clock. Reducing sugar has a suf.

The Cu O should be produced.

The formation of carbocation is involved in the N reaction.

S 2 reaction is a one-step reaction.

Trinolein is an oil.

There are salts of acids in soaps.

There is a suitable leaving group. Phos tions are unimolecular elimination reactions and E1 reac are derived from glycerols.

Proceed via carbocation intermediates.

The heads and tails of soaps andlipids are bimolecular.

Glycine " C double bonds in their hydrocarbon breaking and do not involve any of the other side of the equation.

The simplest a -amino acid is stearic acid.

The combination of two things.

There is less crowding. The acids are recommended in the diet of glycine.

The iso Table 28-2 has the highest electric point for safflower oil. The isoelectric point of glycine is a percentage.

Each molecule needs CH COO- to be denatured.

There are feature problems.

There are two of them that contain phosphate groups.

The Iodine number is 86.0.

The sugars value is 180. The Iodine number is 81.6.

In the case of DNA, proline will not migrate very effectively. ribose will migrate in the case of lysine.

A pyrimidine base is called aspartic sugar. The positively charged purine bases are adenine and guanine. One is not. The answer is (d).

In the case of is. The answer is (d).

The other pyrimidine base is called uracil. The answer is yes.

There is a sequence to AGC. The answer is (b). The answer is Ser-Ala-Ser, Ser-Lys-Ala, Ser-Ala-Lys.

The answer is (d). The answer is yes.

The answer is (d). The answer is (b).

All atoms of an element are 888-609- 888-609- 888-609- 888-609- 888-609- The empirical formula is C6H11O2. 1 mol CO2 forms for every mole C step used to solve a problem and whether or not the ratios remain valid, depending on the number of idea that atoms combine in simple numerical combustion. The exception is 1mol H2O for every 2mol H.

The atomic mass is 51.996 U.

The two-pan balance of the N2H4 mass is the same as that of the conclude two or more isotopes. The "mass" of naturally occurring Au atoms will appear less when mass 196.97g Au>NA is reached.

The product is called KCl(s).

1000 g is equivalent to 1470 cm3. The fraction tural formula is C4H6O2.

The structural formula of acetic acid in rect shows that no atoms can be created or destroyed with an instrument. COOH has the lowest value. There is a group of 1 in. The other four quantities mass were compared.

100 cm is 11 in.

This is now the largest mass because of the increase in the number of Cu atoms from 250.0 to 200.0 mL. It is to 1.000 M C12H22O11. The molecule is more than 1.5mol H2O 7 27 g, but the molarity of the first solution is reduced to 1/3, wrongly, that the tree interacted with its this is now the largest mass. The total amount of water. The final solution is 0.180 M KCl.

There are 4 NH31g2 + 5 O21g2 gas.

The atom has 4 NO1g2 and 6 H2O1l2.

If you don't know the atoms in the formula, you can use the molar and 1.2 mol H2O. We cannot mass by the mass fractions of the elements because of the mass of unreacted bromine. The answer shows the mass of magnesium bromide.

The following facts must be consistent.

230 g * 11 mol C>12.012 g2 11.98 mol C.

The idea that atoms are indivisible is not supported by the factor 0.90.

You can get 21.97 mol H and 3.995 mol H.

The increase in the forming 1mol C2H41g2 is the next line down.

C2H6 is the first line below 21g2 and has an ion concentration of 0.024 M.

The density data is based onclusive based T.

They conform to the ideal gas constant.

OF21R is uncertain. A wavelength of 2O1l2 is suitable for O21R.

It is possible for CaO and BaCO to be seen by the human eye. The explod wavelength is 91.2.

It is possible that BaSO41s2 is in an underground cavern. There would be no reaction to an isolated system.

An open system includes two reduction half-reactions and an acid with a base.

This can happen as seen.

The mass of hot water is twice that of the comet and Jupiter's surface.

There are particles in the agent. A solution is formed.

The greater momenta of the C/ T are the same if the wavelengths are the same.

The amount of heat length from either end of the box is greater than the amount of water required to cover the hump, beyond which the water is not present. Adding particle to those points is how this is done. Air pressure pushes measured amounts of reactants for a reaction up a partially evacuated pipe.

This is not open. The scale is the orbital. The temperature must have gone down after the change from 100 K to 200 K.

Arsenic is a compound.

The system's internal energy decreased.

The energy was transferred across the arrows in the same direction.

The balloon is warm in one direction.

The exothermic, q 6 0, has to be adjusted for the 0.667 L SO CHAPTER 9 21g2

The system has 98.0 kPa electron configuration of Si. The bottom leading to V is 0.743 L SO. The ten core electrons are 21g2.

The process is far from equilibrium and he is not affected by any other gases.

Zeff increases the amount of heat that can be removed.

The function of state is represented by the blue axis. When a process returns a false result.

The strong electron N atom pulls electron density away from the weight oils might become so mobile as to lose repulsions in an anion of high negative charge, creating a large dipole their lubricating properties. Intermolecular forces are stronger with F bonds oil.

The reason for the P/S comparison on moment is the same as the reason for the different elevation and expected trend.

The intermolecular attractions are smaller than the BH3 atoms due to the cation CH3 being in CCl4 and three pairs of London dispersion forces.

The first and last correspond to six electron pairs around a cen that give off heat to the surroundings.

We expect the compound AsF5.

Five bonds formed to H2O1g2.

Equal contributions from the be trigonal bipyramidal are involved. There are no formal charges if the Bragg equation is used.

The wavelength of the wave must be halved if there is a polyatomic ion and at least one atom with a formal tions. 1Bing 2 is required.

Four C60 mole ion are contained in the fcc unit cell. Two Lewis of the N atoms can be drawn, but they must retain a single pair of cules. There are four and eight structures in the unit cell. There are no formal charges for one structure.

One bond to H has a formal charge of sp2 and the formula is based on a unit cell. The formula is called K31C602.

The thermody 3CO2H is referred to as a resonance hybrid by the structure of CH and nonspontaneous.

The excited state of H nonspontaneous process will not occur with 2.

F2 should have a bond order of 1.

The observed is caused by the expansion of the gas in ference of one pair of electrons.

It is possible that the least satisfactory oils might solidify.

C/vapH and C/vapS have constant If and K.

The temperature is raised to 100 degC K by the values.

When 3 mol O2 is converted smaller of the two, the 3O + ] system is 326.4 kJ. The reverse is given as OH -. 2 mol O3 is the relevant equation.

NH2CH2NH21aq2 pK2 is 9.92.

The base ionized reactions are impossible with Kp.

Concentrations are based on mass.

The direction of net change must be in the C ward reaction.

Above the solution, 6H61l2 should follow PH(g) NH3 CH1 CH32COO- + H2O D.

A is xB and PA2 is xP.

+ A - PA2>P

According to the law, P decreased.

NH3CH1CH32COOH + OH- pKb is 11.37.

An inert gas has no effect.

If both components are on a constant-volume equilibrium condition, this will happen.

Composition of the equilibrium mixture will be determined by the vapor pressure of the solution.

The CO2 3 ion can act as a weak base, although it might be found at one pressure of H21g2 caused by forc CO2 3.

The sim is partly offset by the equilibrium 1.0 * 10-14/4.2 * 10-11. Two different solutions are shifting to the left. It's basic that equilibrium shifts in Na CO.

The chief has a higher yield of product.

CH3COO is 100 times larger.

chlorophenol is used to reform slopes.

Three atoms are joined by a single NaCl. It is a pair of unrelated acids.

The freezing point of the solution is Kw/[H3O+].

A concentrated solution of a weak acid may form a Lewis base. The final product has a lower pH than a dilute solution.

The expression K is used into the expression A. The bottle labeled Ka is labeled with the pH through the common-ion effect substitute and contains a more acidic solution. If K is less than 0.02, 10-5 has the acid with the somewhat stronger base than NH3.

A small amount is being added to the material balance.

AgCl2(s) + Cl-1aq2(s)

The overall solution will be absent because of the negative test for that ion. 2m is equivalent to 2.83 0.075 M NH31aq2.

log 2 is considered m log 2.

After starting at the same point, it will work.

The amount of strong acid remaining salt bridge is dependent on the plot. It would still produce a pH L 1. To preserve charge balance, this is the to Cu(s) and half-lives.

Bing 2 has a high pH and a gain in mass at the Cu(s) electrode second-order.

2 e exist. The reaction is similar to lence points. The curve would lose mass at the Zn(s) Figure 20-10).

The reaction is endothermic.

The condition cannot exist between the two points.

C/H is less than Ea for an exothermic.

There is no heat of reaction. In the case where Edeg 6 0, but in the dition cannot exist, this is the second most common occurrence.

The final solution is acidic, so right decrease until equilibrium is reached.

The concentrations are not the same. The solution would remain ment and increase the value of Ecell because of the mechanism that lowers the reaction barrier.

The increase in the rate of reaction caused by is doubled.

There are more collisions per unit time.

They can be assumed to be 0.041 V if Ecell is not found in tables. The potential is dependent on the chloride potential.

The immaterial is what AlF3 will have. The standard reduction potential for higher melting point is the only requirement. The Na+, K+, Rb+ AgNO31aq2 should be concentrated enough to bring a calomel electrode with a different chloride. Dry cells and lead-acid cells run atomic anions.

CaF2 will be affected by the high concentrations of reactants and ion. The formation of F- is derived from the products eventually reach their equilibrium polarizing power, and so it will undergo hydroly ues, where C/rG and Ecell both become 0.

An entirely plausible Ni and Cu are less active than MNO21s2 + Bing 2 O21g2 1M.

N21g2 + 3 H21g2 2 NH31g2 is a solution that compares the rate of disappearance of N geometry around the Be atom. There was a disappearance of H linear to trigonal.

There is a possibility that the Mg(s) is oxi 3 is twice as much as the Ag(s) is less than in pure water great. If the initial and instantaneous dized to CO21g2 is reduced because of the common-ion effect.

The concentration 2 MgO1s2 + C1s2 becomes so throughout a reaction.

A95 is heating the group 2 carbonates. The equation species suggest that the central O atom is sp2 electricity and that the Lewis structures do not conduct the oxide.

O3 was hybridized in O 3.

The first two are easy to do with the Mg2+ ion.

Presumably, when it's satisfactory for describing the bonding six-coordinate complex.

Three N atoms can give an electron large enough to fix the N3- anion.

Bing 2 N21g2 is called pies an antibonding orbital.

The oxygen-oxygen bonds in O3 are slightly different.

The termi shows more positive character in CH32, which leads to all four Cl- ligands in the same plane. The same isomer can't be obtained by compound and forms, which is why AlF3 is an electron deficient.

The Cl atom is smaller than the br atom.

2 in equation 21.29 by 1mol CO in Br atoms does so in a single step, while ion.

110.5 kJ>mol CO1g2 four Cl atoms are in the PCl4 steps.

The emissions and electron can be eliminated by removing one O2 between the ends.

The element is the same after 12 solutions, followed by chemical or elec g rays.

The trolytic reduction to the metal is provided by 3 Be2+. There are 12 units of positive charge for Francium.

The backbone can be maintained with little or no more than two additional O.

The significant period of time at a high activity is CHAPTER 22 O. S.

Refer to Table 25.2 and Figure 25-7 and polyphosphate focus on magic numbers and the relative thick and F, compared to Xe and Cl, makes XeF2 a. The neutral molecule is the sum of the O.S.

A stable nuclide is 21g2 at the [Cd5]3. Cu falls below the Pt anode, and NaI yields I2 at the anode dal.

Attaching to either butan-2-ol will produce OH.

Attaching to one of the will attacks from below the ring is superimposable.

"pentyl alcohol" is not adequate.

The preferred name is pentan-2-ol.

The name 2-pentanol is often used.

The series can only be limited to straight-chain alkanes with unsaturation. A dialdehyde has two p as a terminal atom.

A H ClC radical can be formed by reacting with a Cl polar protic and stabilizing a carbocation.

The SN1 mechanism is responsible for forming cl ether.

L-1 - 2-glucose is the conformer with the methyl group. The position has higher energy and no D-1-2-glucose. If burned, this polypeptide would release more energy.

The net position is at the C-terminal amino acid, where the larger group, - CH3, is located.

There are four stereoisomers attached to the 2-bromo-3 formation.

OH groups could have the two Br atoms on opposite sides of the obtained because hydration proceeds through hydrogen bonds between molecule and its mirror image, making a total carbocation. The carbocation can be attacked randomly, but not in the stereoisomers.

The online chapter, Chapter 28 is indicated by the letters preceding a page reference.

1046-1049 oxygen is used in the Henderson-Hasselbalch equation.

Concentration change reactions are expressed as ruff degradation.

The gases are noble.

The atomic mass is relative to carbon-12.

The numbering of groups is explained on page 52. The metals are and the nonmetals are not.

The International Union of Pure and Applied Chemistry endorsed the version on May 1. Atomic mass are from Pure Appl. They are given five figures. The IUPAC announced the verification of the discoveries on December 30, 2015. The symbols of these elements are expected to take several months to complete.

The mass numbers of the most stable radioactive elements are listed.

1 joule 1J2 is equal to 1 N m.

PNIPAM was the first temperature-responsive polymer.

A PNIPAM hydrogel has a unique property that makes it transition from a hydrated state to a dehydrated state. The temperature is 32 degrees.

Instructors can maximize class time with a variety of assessments that are easy to assign and personalize to their students' learning styles. The assessments help students get ready for class. The gradebook gives insight into student and class performance before the first test. Instructors can spend class time where students need it the most.

  • 1. Matter: Its Properties and Measurement 1-1. The Scientific Method 1-2. Properties of Matter 1-3. Classification of Matter 1-4. Measurement of Matter: SI (Metric) Units 1-5. Density and Percent Composition: Their Use in Problem Solving 1-6. Uncertainties in Scientific Measurements 1-7. Significant Figures Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 2. Atoms and the Atomic Theory 2-1. Early Chemical Discoveries and the Atomic Theory 2-2. Electrons and Other Discoveries in Atomic Physics 2-3. The Nuclear Atom 2-4. Chemical Elements 2-5. Atomic Mass 2-6. Introduction to the Periodic Table 2-7. The Concept of the Mole and the Avogadro Constant 2-8. Using the Mole Concept in Calculations Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 3. Chemical Compounds 3-1. Types of Chemical Compounds and Their Formulas 3-2. The Mole Concept and Chemical Compounds 3-3. Composition of Chemical Compounds 3-4. Oxidation States: A Useful Tool in Describing Chemical Compounds 3-5. Naming Compounds: Organic and Inorganic Compounds 3-6. Names and Formulas of Inorganic Compounds 3-7. Names and Formulas of Organic Compounds Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 4. Chemical Reactions 4-1. Chemical Reactions and Chemical Equations 4-2. Chemical Equations and Stoichiometry 4-3. Chemical Reactions in Solution 4-4. Determining the Limiting Reactant 4-5. Other Practical Matters in Reaction Stoichiometry 4-6. The Extent of Reaction Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 5. Introduction to Reactions in Aqueous Solutions 5-1. The Nature of Aqueous Solutions 5-2. Precipitation Reactions 5-3. Acid-Base Reactions 5-4. Oxidation-Reduction Reactions: Some General Principles 5-5. Balancing Oxidation-Reduction Equations 5-6. Oxidizing and Reducing Agents 5-7. Stoichiometry of Reactions in Aqueous Solutions: Titrations Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 6. Gases 6-1. Properties of Gases: Gas Pressure 6-2. The Simple Gas Laws 6-3. Combining the Gas Laws: The Ideal Gas Equation and the General Gas Equation 6-4. Applications of the Ideal Gas Equation 6-5. Gases in Chemical Reactions 6-6. Mixtures of Gases 6-7. Kinetic-Molecular Theory of Gases 6-8. Gas Properties Relating to the Kinetic-Molecular Theory 6-9. Nonideal (Real) Gases Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 7. Thermochemistry 7-1. Getting Started: Some Terminology 7-2. Heat 7-3. Heats of Reaction and Calorimetry 7-4. Work 7-5. The First Law of Thermodynamics 7-6. Application of the First Law to Chemical and Physical Changes 7-7. Indirect Determination of rH: Hess's Law 7-8. Standard Enthalpies of Formation 7-9. Fuels as Sources of Energy 7-10. Spontaneous and Nonspontaneous Processes: An Introduction Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 8. Electrons in Atoms 8-1. Electromagnetic Radiation 8-2. Prelude to Quantum Theory 8-3. Energy Levels, Spectrum, and Ionization Energy of the Hydrogen Atom 8-4. Two Ideas Leading to Quantum Mechanics 8-5. Wave Mechanics 8-6. Quantum Theory of the Hydrogen Atom 8-7. Interpreting and Representing the Orbitals of the Hydrogen Atom 8-8. Electron Spin: A Fourth Quantum Number 8-9. Multielectron Atoms 8-10. Electron Configurations 8-11. Electron Configurations and the Periodic Table Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 9. The Periodic Table and Some Atomic Properties 9-1. Classifying the Elements: The Periodic Law and the Periodic Table 9-2. Metals and Nonmetals and Their Ions 9-3. Sizes of Atoms and Ions 9-4. Ionization Energy 9-5. Electron Affinity 9-6. Magnetic Properties 9-7. Polarizability Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 10. Chemical Bonding I: Basic Concepts 10-1. Lewis Theory: An Overview 10-2. Covalent Bonding: An Introduction 10-3. Polar Covalent Bonds and Electrostatic Potential Maps 10-4. Writing Lewis Structures 10-5. Resonance 10-6. Exceptions to the Octet Rule 10-7. Shapes of Molecules 10-8. Bond Order and Bond Lengths 10-9. Bond Energies Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 11. Chemical Bonding II: Valence Bond and Molecular Orbital Theories 11-1. What a Bonding Theory Should Do 11-2. Introduction to the Valence Bond Method 11-3. Hybridization of Atomic Orbitals 11-4. Multiple Covalent Bonds 11-5. Molecular Orbital Theory 11-6. Delocalized Electrons: An Explanation Based on Molecular Orbital Theory 11-7. Some Unresolved Issues: Can Electron Density Plots Help? Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 12. Intermolecular Forces: Liquids and Solids 12-1. Intermolecular Forces 12-2. Some Properties of Liquids 12-3. Some Properties of Solids 12-4. Phase Diagrams 12-5. The Nature of Bonding in Solids 12-6. Crystal Structures 12-7. Energy Changes in the Formation of Ionic Crystals Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 13. Spontaneous Change: Entropy and Gibbs Energy 13-1. Entropy: Boltzmann's View 13-2. Entropy Change: Clausius's View 13-3. Combining Boltzmann's and Clausius's Ideas: Absolute Entropies 13-4. Criterion for Spontaneous Change: The Second Law of Thermodynamics 13-5. Gibbs Energy Change of a System of Variable Composition <=rGdeg <=rG 13-6. <=rGdeg and K as Functions of Temperature 13-7. Coupled Reactions 13-8. Chemical Potential and Thermodynamics of Spontaneous Chemical Change Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 14. Solutions and Their Physical Properties 14-1. Types of Solutions: Some Terminology 14-2. Solution Concentration 14-3. Intermolecular Forces and the Solution Process 14-4. Solution Formation and Equilibrium 14-5. Solubilities of Gases 14-6. Vapor Pressures of Solutions 14-7. Osmotic Pressure 14-8. Freezing-Point Depression and Boiling-Point Elevation of Nonelectrolyte Solutions 14-9. Solutions of Electrolytes 14-10. Colloidal Mixtures Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 15. Principles of Chemical Equilibrium 15-1. The Nature of the Equilibrium State 15-2. The Equilibrium Constant Expression 15-3. Relationships Involving Equilibrium Constants 15-4. The Magnitude of an Equilibrium Constant 15-5. Predicting the Direction of Net Chemical Change 15-6. Altering Equilibrium Conditions: Le Chatelier's Principle 15-7. Equilibrium Calculations: Some Illustrative Examples Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 16. Acids and Bases 16-1. Acids, Bases, and Conjugate Acid-Base Pairs 16-2. Self-Ionization of Water and the pH Scale 16-3. Ionization of Acids and Bases in Water 16-4. Strong Acids and Strong Bases 16-5. Weak Acids and Weak Bases 16-6. Polyprotic Acids 16-7. Simultaneous or Consecutive Acid-Base Reactions: A General Approach 16-8. Ions as Acids and Bases 16-9. Qualitative Aspects of Acid-Base Reactions 16-10. Molecular Structure and Acid-Base Behavior 16-11. Lewis Acids and Bases Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 17. Additional Aspects of Acid-Base Equilibria 17-1. Common-Ion Effect in Acid-Base Equilibria 17-2. Buffer Solutions 17-3. Acid-Base Indicators 17-4. Neutralization Reactions and Titration Curves 17-5. Solutions of Salts of Polyprotic Acids 17-6. Acid-Base Equilibrium Calculations: A Summary Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 18. Solubility and Complex-Ion Equilibria 18-1. Solubility Product Constant, Ksp 18-2. Relationship Between Solubility and Ksp 18-3. Common-Ion Effect in Solubility Equilibria 18-4. Limitations of the Ksp Concept 18-5. Criteria for Precipitation and Its Completeness 18-6. Fractional Precipitation 18-7. Solubility and pH 18-8. Equilibria Involving Complex Ions 18-9. Qualitative Cation Analysis Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 19. Electrochemistry 19-1. Electrode Potentials and Their Measurement 19-2. Standard Electrode Potentials 19-3. Ecell, <=rGdeg and K 19-4.Ecell as a Function of Concentrations 19-5. Batteries: Producing Electricity Through Chemical Reactions 19-6. Corrosion: Unwanted Voltaic Cells 19-7. Electrolysis: Causing Nonspontaneous Reactions to Occur 19-8. Industrial Electrolysis Processes Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 20. Chemical Kinetics 20-1. Rate of a Chemical Reaction 20-2. Measuring Reaction Rates 20-3. Effect of Concentration on Reaction Rates: The Rate Law 20-4. Zero-Order Reactions 20-5. First-Order Reactions 20-6. Second-Order Reactions 20-7. Reaction Kinetics: A Summary 20-8. Theoretical Models for Chemical Kinetics 20-9. The Effect of Temperature on Reaction Rates 20-10. Reaction Mechanisms 20-11. Catalysis Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 21. Chemistry of the Main-Group Elements I: Groups 1, 2, 13, and 14 21-1. Periodic Trends and Charge Density 21-2. Group 1: The Alkali Metals 21-3. Group 2: The Alkaline Earth Metals 21-4. Group 13: The Boron Family 21-5. Group 14: The Carbon Family Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 22. Chemistry of the Main-Group Elements II: Groups 18, 17, 16, 15, and Hydrogen 22-1. Periodic Trends in Bonding 22-2. Group 18: The Noble Gases 22-3. Group 17: The Halogens 22-4. Group 16: The Oxygen Family 22-5. Group 15: The Nitrogen Family 22-6. Hydrogen: A Unique Element Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 23. The Transition Elements 23-1. General Properties 23-2. Principles of Extractive Metallurgy 23-3. Metallurgy of Iron and Steel 23-4. First-Row Transition Metal Elements: Scandium to Manganese 23-5. The Iron Triad: Iron, Cobalt, and Nickel 23-6. Group 11: Copper, Silver, and Gold 23-7. Group 12: Zinc, Cadmium, and Mercury 23-8. Lanthanides 23-9. High-Temperature Superconductors Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 24. Complex Ions and Coordination Compounds 24-1. Werner's Theory of Coordination Compounds: An Overview 24-2. Ligands 24-3. Nomenclature 24-4. Isomerism 24-5. Bonding in Complex Ions: Crystal Field Theory 24-6. Magnetic Properties of Coordination Compounds and Crystal Field Theory 24-7. Color and the Colors of Complexes 24-8. Aspects of Complex-Ion Equilibria 24-9. Acid-Base Reactions of Complex Ions 24-10. Some Kinetic Considerations 24-11. Applications of Coordination Chemistry Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 25. Nuclear Chemistry 25-1. Radioactivity 25-2. Naturally Occurring Radioactive Isotopes 25-3. Nuclear Reactions and Artificially Induced Radioactivity 25-4. Transuranium Elements 25-5. Rate of Radioactive Decay 25-6. Energetics of Nuclear Reactions 25-7. Nuclear Stability 25-8. Nuclear Fission 25-9. Nuclear Fusion 25-10. Effect of Radiation on Matter 25-11. Applications of Radioisotopes Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 26. Structures of Organic Compounds 26-1. Organic Compounds and Structures: An Overview 26-2. Alkanes 26-3. Cycloalkanes 26-4. Stereoisomerism in Organic Compounds 26-5. Alkenes and Alkynes 26-6. Aromatic Hydrocarbons 26-7. Organic Compounds Containing Functional Groups 26-8. From Molecular Formula to Molecular Structure Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problem Self-Assessment Exercises
  • 27. Reactions of Organic Compounds 27-1. Organic Reactions: An Introduction 27-2. Introduction to Nucleophilic Substitution Reactions 27-3. Introduction to Elimination Reactions 27-4. Reactions of Alcohols 27-5. Introduction to Addition Reactions: Reactions of Alkenes 27-6. Electrophilic Aromatic Substitution 27-7. Reactions of Alkanes 27-8. Polymers and Polymerization Reactions 27-9. Synthesis of Organic Compounds Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problem Self-Assessment Exercises
  • 28. Chemistry of the Living State on MasteringChemistry on (www.masteringchemistry.com)
  • Appendix A. Mathematical Operations
  • Appendix B. Some Basic Physical Concepts
  • Appendix C. SI Units
  • Appendix D. Data Tables
  • Appendix E. Concept Maps
  • Appendix F. Glossary
  • Appendix G. Answers to Practice Examples and Selected Exercises
  • Appendix H. Answers to Concept Assessment Questions
  • Index
  • Back Cover

A metalloid is 2.2 3 103 g/ cm2, 2.2 3 104 kg/m2 B. -26.1 oC of -465 oF is not possible because it is a group metalloid.

The water level will not change.

There are feature problems. The mass of information is obeyed or violated.

The mass should be compared one at a time. The results have to be of the density.

The answer is a natural law. The current theory can be compared.

The answer is yes. The chemical answer is (c).

Heterogeneous have 3 significant figures and the answer pound is 3:2.

If a magnet is shows 2, (c) should have 2 significant figures are entirely consistent with the Law of drawn through the mixture, the iron filings and the answer shows 3, (d) 2.83 has the correct Multiple Proportions because the same two will be attracted to the magnet and The answer is (d) and (f). The answer reacted together to give a different mixture of com and water. The answer is (b). There is a ratio of small positive integers for a fixed not. Student A is more accurate than student B. These results are pure. It will float to more precise. The answer is (b). It would be significant. The answer is (d).

If the mixture is left, compound A will settle to the bottom.

Millikan found 0.80 g oxygen. He had 3.39 g of unreacted O for that of the electron.

Use the mass of a 64 Gd.

Na is a main-group metal.

Re is a transition metal. The electron is a hydrogen ion.

Group 17(7A) has a main-group nonmetal.

Kr is a nonmetal.

An electron is U.

Several possibilities exist for a nuclide.

The compound is the symbol of the element involved, the number of electrons and the name.

The oxidation state of Cu is +2.

The answer is (b).

The answer is yes.

The answer is yes. The answer is (d).

There are no chlorine atoms that have an answer.

The answer is yes. The answer is (d). The answer is (b).

The vapor will be due to the presence of the isotopic mass.

The mole elements in group 16(6A) are similar to the mole elements in S: O.

Each Se and Te has 11 moles of H atoms. The peri empirical formula has most of the elements in it.

The Fe pound is C H O.

The compound is C H O Cl.

The formula is C H O Cl.

The oxidation state of 1022 Cu is zero.

Each chlorine has an O.S.

The 3rd generation has an O.S. There is an O.S. for each S.

Each Hg has O.S.

There is cium fluoride, iron(II) oxide, and chromium(III) increasing.

There are feature problems.

2 7 per mole of the compound will produce the balance; alternatively, it can be as large H SO.

Both "a" and "b" are consis 2 2 CH OH.

A total of

The required mass is 2.500 kilograms.

The answer is (d).

The answer is yes.

The answer is (d).

The answer is (b). The answer is (d).

There are feature problems.

The compound is dolomite.

The solution is a 0.500 M KCl solution.

The answer is (b). The answer is yes.

All of the reactions have a 10% chance of success.

The volume of CHAPTER 5 is divided by the ratio. The answer is (b). The answer would be 20:1. The number is (d). The answer is yes.

The answer is yes.

The answer is yes. The answer is yes.

The answer is yes. There are many combinations that could be used.

The answer is (b).

51.79 g mol-1 is the AlPO (s) (b) Ba2+ (aq) + of Li P. The answer is (d).

The answer is (d).

Chapter 4 left some Cu unreacted.

This is an oxidation-reduction reaction.

Vanadium and manganese are both reduced.

5.29 g will be run.

A small amount of ial present be detected.

The sample can be lost during the analysis.

I produced 1.34 kg AgNO.

30 g of KNO is needed.

The molar mass of NO is 2 MnO (s) + 2 ClO 2 (aq) + 2 OH2 (aq).

NH and H O are oxidizers.

About one seventh as much is 6 ClO + 6 OH2 + 5ClO 2.

It is less dense than air.

No is reduced.

5 NO 2 (aq) + 2 MnO 2 (aq) + 6 H+ (aq) CO 5 0.27mmHg.

3MnO 2 and 4 OH2 are added together to make a total of 661m/s.

Possible Lewis structures are 16 H S(g).

Similar results will be achieved by HC H O.

The oxidizing agent is propionic acid.

The weak elec reducing agent is Ammonia.

The oxidizing agent is H O.

No gas escapes; 0.077 M NaOH proof. The answer is (d).

The bag is almost bursting.

The mula is C H.

The density of CO is very high.

There is no reaction.

The balloon won't rise in the air.

It will not happen.

The volume has increased by 50%.

There are feature problems.

HCO 2 + H+ is (b). The answer is (d).

It is (c). The answer is yes.

This isn't a redox equation.

This is a chemical reaction. The answer is (b). The answer is (d).

There are feature problems. The answer is yes. The answer is yes.

The answer is (b). The answer is (d).

The O.S. is false if the compound isnitryl floride. One atom of O, Thionyl that of Cr is +6. No floride is 1 atom of Sulfuryl floride.

Chapter 6 has some Ar(g) mixed in.

With the same cross sectional area, magnesium will react with 3 N (g) + 2 Br2 (aq).

The densities are different.

The answer is (b).

The answer is yes. The answer is yes. The answer is yes.

The answer is (d). The answer is (b).

The answer is (c).

The answer is (d). The answer is yes.

The convention is set to 0.

The answer is yes.

It is unlikely that -206.0 kJ/mol compound will be near zero.

The answer is (b).

One can of CO is theoretical. The answer is yes.

The proportional to D is what shuts off the heat source. The principle of heat conduc liquid is used to convert the electric eter of the tube into a stove.

The heat energy would be transferred to the surface because of it's heat capacity. The heat is still being supplied to the pot. The pro answer is sewage gas. The answer is (b).

Coal gas is done by 4.89 kJ.

The work is done by the system.

There are feature problems. This is E for n is produced by Methanl.

NaOH was added and the amount was 1.0 M citric 1, or 16.7%.

6 is incorrect.

All quantum numbers are allowed.

-505.8 kJ/mol Ag CO was formed.

2 is incorrect.

2 is incorrect. The product of the reaction is heat.

The temperature was at the exact proportions.

1.21 J/K (1,1,0, 1>2) is incorrect. The heat evolved to 105 kJ. The mass to heat is the same as 65.59 kJ ume.

At this point, the temperature is a maximum.

2 is incorrect.

The heat evolved.

The minimum wage is +152 J.

The answer is yes. The number is (d). The answer is yes. The temper is a b. There are unpaired electrons in a Sn atom.

This situation is impossible.

One unpaired electron is the energy of the atom.

The frequencies of the nodes.

The zinc is diamagnetic.

There is a plot of radial probability distribution.

The radiation comes from the sun.

The boiling point temperature was over 300 K.

Unk represents element 118.

n is the number of sition

Line B is for the transition and the boiling point is K.

Xe relation C/r C/p U h/(4p) shows that mercury can't be obtained with visible light.

There are feature problems.

The slope density shows zero.

It is tainty principle. The corresponding 97.2 nm, 486.1 nm, 1875 nm, 102.5 nm, falls a bit, rises again, and falls back to the axis, are exactly known. The two spectrums are not the same.

C/r and C/p are both 0.

Atomic C/ r and C/p are not weights. The atomic mass must be greater than or equal to h/(4p).

The table has subshell ments that they differ in. As originally proposed, the energy levels are not degenerate and the elements are arranged in such a way that they don't conform to the order of increasing atomic number. The amount of positive that can be allowed is the amount of effective gral values. The charge from the nucleus that the valence shell possible integral values in a certain range have are three-dimensional regions of space of the electrons actually experiences is a planar pathway. No new elements are possible in which there is a high chance of finding less than the actual nuclear charge.

Its position and speed have an effect.

The sizes of atoms are not always known at the same time. The electron in an orbital, degenerate, and they increase with atomic number is due to the fact that elec does not have the same shape. Their difference lies in the way trons are added. The orientation of the planets is similar to the subshell. Each electron is in motion. The answer is (a). The netic radiation is fixed because of the ineffective shielding.

The valence shell has the highest quantum Ca2+, F2 and Al3+. The number has the highest energy. They are isoelectronic without having noble-gas elec r4p.

The charged electron is being separated from the effective nuclear charge felt by the greater, and the positively charged cation is a process that must electrons in that orbital.

The electron is being removed from a species. The answer is yes. The answer is yes.

The answer is (b). The answer is yes.

The answer is (d). Cs+: remove an electron.

If there is an odd num configuration of Ar, there is no way to pair the electrons up. The stable [Ar] configuration is being lost by many atoms.

Those with visible light should have a follow higher first ionization energy values for small values.

There is a slight energy advantage to Rb and K.

I N I have visible light and those with high val are those with one extra electron. Again from pairs are Ar/Ca, Co/Ni, Te/I and Th/Pa.

With visible light, cl bonds are the most effective.

The most red in it are the ionized energies.

The reverse of electron affinities is compatible with both (b) and (e).

The electron is from the nuclear charge.

The nucleus has 5249 kJ/mol.

There are 66 feature problems.

The value of A is calculated.

It is most likely the equiv low electron affinities.

There is an answer.

One can think of b as a representation of Ne.

The radius is decreased by 1 if the kJ trons is greater.

Ga structures have no formal charges.

There are two bonding pairs of electrons. CaO is an ionic compound.

The answer is yes.

The angle of the number of electrons is incorrect.

It was a bit smaller by the lone pair.

The angles are very close to each other.

It's H O, it's polar.

The bonds cancel out.

H bond is close to midnight.

The bond lengths are 195pm.

O are used to decide between alternative Lewis, the orbital overlap between P and the structures, while oxidation state is used in bal surrounding Cl atoms will be different and ancing equations and naming compounds.

Group 17 will have slightly different pounds.

H is equal to 2233 kJ/mol.

The answer is (b). The answer is yes.

The answer is yes. The answer is yes.

There is a representation on the right.

The answer is (b). The answer is yes.

The right is for SiF.

The answer is yes.

The answer is (d).

The answer is (e).

The answer is yes.

Expansion of octets is required for SF and ICl.

The others don't. Neither is completely linear.

The Tetrahedral I is called 0.00192.

The angle becomes.

The P2O2P bond is not linear.

I made per gram of that material.

When an atom has one lone two other atoms, the central N is attached to etry.

The molecule's geometry is linear.

The N and N bond results from the two other atoms in an atom.

O bond is formed by the overlap of the full F.C.

The atoms will form a p bond.

I will be tronegative atom.

The N atom is centered above the molecule.

The molecule is a pyramidal shape.

The molecule is in a pyramid.

Weak bonds are longer bonds.

The oxygen atom is bent.

3 hybrid, bond order is 2.0.

The bond angle is 120o.

The atom is called B.

The shape is different between sigma and pi bonds.

S bonds are the single bonds in this structure.

The bond angle is at C.

The bond results have 109.5o angles.

The bonds are made of atoms. The central atom is N.

The central atom is called Cl.

The ion is bent in shape in order to have a bond.

The answer is yes. The answer is yes.

The answer is yes. The answer is (b).

The answer is yes. The answer is (d).

To form an He molecule, 1 must unite.

The possible configuration is s21ss*0 1ss22ss0 2s.

The bond order is 2.

The diagrams for C and N are square pyramidal.

The answer is yes.

3 for NO+ and 2.5 for N is the bond order.

NO+ is a Lewis structure.

The answer is yes.

The answer is (e). The answer is (d).

The answer is (b). There are 5 s bonds.

The hybrid eH3 has 6 p electrons. The C H molecule is gle delocalized on the oxygen.

There is a requirement for delocalized molecular orbitals.

There is a requirement for delocalized molecular orbitals.

Na2 has 22 electrons.

It should have the highest boiling point.

3 2 in Na is very similar to H.

Like honey, molasses serves as a site for the formation of ice crystals.

Supercooling is destroyed smaller than C H if CH NO are present in January.

The molecule is polar.

The Viscosity generally alternative explanation follows. As the temperature decreases, the strong dipole2dipole forces increase. The molasses at low temperature is very slow because the gas coming out of solution is endothermic.

There is a scientific from the cooled liquid that causes it to freeze.

All sion forces were dominant in the area.

The water's tempera is endothermic, meaning it drops when it's in the liquid state. The requires energy when the temperature goes up.

The temper the container has been converted to H O(s).

Si P is reached.

As the liquid evaporates, liquid will decrease.

2 hybrid orbitals of the boron and nitro are very little change in volume because heat must be applied.

As ionic charges increase, the C becomes smaller.

LowerMelting point is higher than CaO.

The ionic forces become weaker.

The pressure of water is 23.8mmHg when the vapor is placed on top of the first layer. The vapor spheres fit into the cracks in the layer pressure for isooctane.

The layer below is expected to be relatively weak because of the London forces between HCl and its spheres.

No first layer sphere is visible through the dipole2dipole attractions.

London forces are important.

Substances that can be liquid at room Dipole2dipole interactions are important.

H bonds can be found in liquid form at 20 oC.

London forces are weak.

It is far below 43 atm. The two top unit cells in the diagram are unable to hold liquid at this pressure.

The small square has pressure.

The other hand is very reached and polar. The unit cell has 0.22 kilograms. The cloth or leather has a Ca2+ ion to F2 ion ratio. The liquid in the can is Ca F or CaF.

When the can is opened, gas bub TiO.

The water is repelled by the carbonated beverage for a total of one Ti4+ corner ion per unit cell.

The unit cell contained 1.42 kJ mol21.

169 K O22 is contained in the unit cell.

Four O22 ion per unit cell is the answer.

A consequence of something. The answer is (b). The answer is yes.

The answer is yes. The answer is (d).

The anwer is. Four formula units per unit cell of the universe.

It's out of place.

Positive mass is: N F Ar O Cl.

A smaller cation will cause the water to boil. In exothermic lattice energy, hydrogen bonding is disrupted.

The value of C/vapHo is smaller if there is too little vapor.

If it's too much before dispersion. When the case forms, there is a vapor at 1 atm pressure.

The CCl will be in the energy at higher temperatures.

The answer is yes. The answer is (d).

This will continue until all of the liquid is at the higher melting point because it takes a lot of addition.

The solid will quickly consume the remaining gas.

The highest melting attraction would be between them. The answer is yes.

The CHAPTER 13 becomes more ordered at 100 oC because of the quantity of heat needed.

At low motion, this is true.

83.0 J mol-1 K-1 was spontaneously in the forward direction.

2574.2 kJ mol21 goes to completion temperature.

C/rGo is -70.48 kJ mol-1 tion.

There are feature problems.

The equilib increases when 3NO oxygen is removed immediately. Ksprium to shift to the right continuously.

K is 5 and is domly oriented. The reaction was not planned.

The cucumber contain ionic solutions.

There are feature problems.

The room tempera is centrated with carbon dioxide. When we combine two reactions that are expected to be very low.

The value of the universe is reduced if flowers and pickles are eaten.

The most depressed should be oxalic acid.

Carbon should be reduced by ZnO. The decom Suggestion 2 contained 46 g of NH Cl.

The answer is (d).

The temperature is above 1850 oC.

As temperature increases, 1.56 3 more stable.

The volume would become less stable if CO(g) became less stable.

N is 65.3%, volume is 34.62%.

29.3% H O, 0.73 atm.

There are feature problems.

As a taneous reaction, the composition of HCl(aq) changes.

2 CO(g) + O contains a benzene ring, which can be used to make 2CO2(g)soluble in benzene.

Two groups bond hydrogen to water.

C(s) + O2(g) changing composition.

The reaction 3 2 C(s) + O 0.12 has a boiling temperature of 120 oC.

The temperature is degC 2 CO(g) water.

It will have to be larger than its percent by mass.

This wouldn't necessarily be true of other is. The answer is (d).

The answer is (d).

The answer is yes.

The answer is yes.

4.36 3 1016 atoms are e. The answer is yes.

The answer is yes.

Chapter 15 is (a). The answer is (b).

There will be no reaction.

The forward reaction should happen.

The forward reaction should happen.

10 - 3, 3OH - 4 n are all equal to 0.0725 mol.

10% of the H O+ produced by water self will shift to the left.

The pH was 0.17% and it was equivalent to 32 g CH CO C H and 68 g H O.

Ka is 5.3 * 10-2

The stronger acids in the pairs are CH FCOOH.

0.154 M, [V2+] is equal to 0.0057 M.

There was more NO(g) formed.

Lewis acid is a base.

Hb:O is reduced.

S O 22 is a solid.

The fraction reacted is 99.9925%.

Kc is 0.12 mol CO and 0.16 mol H.

There are feature problems.

C(or) is 6 3 10-4 M and C(aq) is 4 3 10-4 M.

The answer is (d).

The answer is (b).

The answer is yes.

There is more produced.

Less is made.

Less is made.

The base is 243H 24.

The acid is 0.82.

3H3O+4 is 4.0 with a pH of 13.40

I have 0.033 mol.

The Lewis acid is H+, which is supplied (b) 11.79.

The els of ionization are not seen here.

Not much compared to the H O+.

NH and NH will not come up with a solution.

There are feature problems.

The answer is yes.

The color of acidic solu is changed by F 2,4-Dinitrophenol. The answer is (e).

The answer is (b).

0.05 M NH 0.06 M NaOH 0.05 M is acid and base.

The solution is simple.

1.2 M is 2.14 3 10-12 M.

The answer is (b).

The answer is (d).

The solution's pH is not known in advance. Acid is H O and base is O2.

O is 0.150 M.

Adding a solution will affect acid, base and SO. Lewis base forms acetic acid.

If not enough is achieved, this will be achieved.

Red mately less than the original amount.

This is a good indicator.

The third protons can be removed from H PO by removing the pH at the equivalence point.

No f(H will hydrolyze in water.

The basic solution will be 250 mL.

The equivalence point has a pH of 7.

A strong base reacts with acetic acid.

There is a sketch in 49a.

There are feature problems.

The answer is yes. The answer is (d).

The answer is (b). The answer is (b).

The answer is yes.

The answer is (b). The answer is (b).

The solution will remain.

There will be no precipitation.

2 OH-(aq) + Pb2+

Pb (OH) may be formed by Cu(OH).

The presence of Ag+ may be overstated.

6 H O(l) : 4[Al(OH) ]-(aq).

Edeg 0.800 V.

Mass dissolved Ag SO is 0.702 g.

There are feature problems. Edegcell is 2.476 V and the Ag+(aq) to Ag(s) tion is 3.03.

The oxidation of Zn(s) to Zn2+(aq) in an ammonia solution is the answer. The answer is yes.

The answer is (b).

The answer is yes.

It is not related to pH.

It is not related to pH.

NH is the answer.

The answer is (b). The answer is (d).

There is no remaining substance.

It will decrease the amount of 2 Al3+.

There will not be a form of precipitation.

CuCO is found in NH and CuS cell.

K sp is a combination of 3Ra2 and 43IO3 and Edegcell is a combination of 2.42 V.

To the left of the reactants.

If a half-reaction with H+ and Ag+ is present.

Yes, Sn(s) + 2 Ag+(aq)

2 e- : Cd(s); sent.

Yes, 2 In(s) + 3 Cd2+(aq)

One example is silver ion.

The method is not feasible because another half-cell in the case is not a complex ion with nitrate ion.

The forward reaction decreases the potential of the complex ion and should be even more so.

Until the value of the product is more positive than that for situa Edegcell, we expect it to be a little larger. The AgI(s) should occur if reaction (2) is preferred over Edegcell. If it is formed, it should case. Decrease [H O+] is maintained just a bit higher than react with Sn(s) to form Sn2+.

Proceed the same way as to the solution for 20.100.

The answer is (b).

The second-order reaction is in HI at 700 K.

The answer is (d). The answer is yes.

The answer is yes. The answer is (d).

The answer is yes.

The aluminum-air cell has a highmol-1min-1.

The cell is labeled 1.719 V.

Increasing [A] increases the half-life occurs to the left.

Edegcell is 2.84 V.

A scratch tears the iron and exposes the pendent.

The rate of reaction increases as the square of Zn(s) + Fe2+(0.0010 M) increases. Blue is expected in the A.

O and H continue to form.

The reaction after transformation into a cathode. Although the collision fre metal would have a positive charge and no CHAPTER 20 would increase in percentage.

The net effect of using a catalyst is to decrease the amount of shielding needed for the metal.

The first 400 seconds will be taken over by oxidation.

A larger fraction of the molecule have trode as substitute.

First-order in H O is required.

Requires an appliedvolt of 1.56 3 103mmHg.

The slow step is 1079.

E is 0.223 V.

The denominator becomes contact between the two objects.

The rate law is at 50 oC.

There are feature problems.

-36.033 3 104 J.

The rate of a reaction is slowed by the answers to practice examples and selected exercises.

The original reaction is most likely Na O and com ferent A value.

There is a metal determined reaction order.

Y is calcium cyanamide and Platinum is non compound.

The present is Na B O # 10 H O(s) + H SO.

The rate of the reaction is influenced by 4 BCl + 3 LiAlH.

3 Li2(s) + 3 Al2(s)

N O is H O + N O.

3 CaSO (S) + 3 H O(g)

V, mL 3 NO -

There will be precipitation.

It's reason duced.

It shouldn't be an easy or rapid process because of the charge density and polarizing mL.

It is easier to drive off the coordinated. The answers are (b) and (e). The water is heated by the solid.

The answer is (d).

The answer is yes. There are two produced.

The hydration half-life doubles with each successive half-life sphere of the Ca2+ ion, so the reaction is second-order.

The neutral pH is 2.312 M CaCl # 6 H O.

2 Na(s) + O (g) is an estimated half-life.

The method with the best results is -1 + k23A4.

The answer is (b). The answer is violet.

The answer is yes.

2 Li CO.

2 Na(Claq)-2 H O (l) were transferred.

2 NaNO (aq) + 3 NO (g) + proper conditions for the desired reactions are the rate of the slow step of the mechanism.

This is the same as the NO (g) + H O(l).

The statement is false because H2SO4 form CO.

Eventually, the conversion occurs.

3 SiO (s) and 4 Al(s) coal.

There is a charge.

There are feature problems.

The answer is (f).

To the left lies equilibrium.

To the left lies equilibrium.

To the right lies equilibrium.

A large polarizable ion is the SO 2- ion.

The oxidation state and hydrogen atoms cation with a high polarizing power will polar for structural purposes because of aluminum.

The metal is beneath it. The answer is (b).

H H H H aluminum atoms add up to 21.

2BBr (l) + 3 H (g) : 2 B(s) + 6 HBr(g) +21

CaF (s)+H SO.

The reaction will be completed.

The reaction was not planned.

The reaction was not planned.

Si(s)+4 NaF(s) which it is exposed is neither acidic nor dense.

B O (s)+3 H O(g) strong acid can't be used because it will hurt I and I-.

The atmosphere is PbCO (s)+2 NaNO (aq)+H O(l)+CO (g)

2 KMnO4 was decomposed by con lowing balanced chemical equation.

Adding acidic solution of KMnO will cause the dispropor S to form.

Edegcell for the reaction is positive.

Pt l is 353 nm.

Bi O is the most basic, P O is 2 HNO and NO.

The mass percent of P is given by 2 nos.

2 H O(l) + 2 I.

The mass of P O displaces another element from the solution.

Ity decreases from top to bottom.

The group below it has an O value of 8 3 10-5 M.

The solution is still acidic.

XeF + 3 H O to displace O from water is F.

H XeO (g) + 4 HF(aq) + 2 H+ (aq) + 2 e-, the halogens reacts with water to form H.

O + 4 H+ + 4 e-.

There is no electrons.

The final cell voltages are 0.030 M and 0.060 M.

Both molecule are V shaped and occur under standard con electrons.

C/fHo is the number of kJ mol-1.

The F bond angle to decrease hydrogen is twice as bad as the volume of oxygen. This result supports the ideal bond angle.

We expect C/fSdeg 6 0 to be the mole of gas. A diamag reaction is also unfavorable because trons are pairs in O.

There are feature problems.

The going to completion is produced by CaH.

The answer is (d).

CaSO + 2 HCl + is (c) The answer is yes.

H O(l) + SO is (d). The answer is (b).

2 KClO (s) is a combination of 2 KCl(s) and 3 O.

A variety of complex ion. CuO(S) + 2 H+(aq) + e- : Cu+(aq) + H 4 H O(l) + 2 NO(g)

When the anion is colored, FeO(s) + 2 H+(aq) occur. 2 H + 2 H + 2 H + 2 H + 2 H + 2 H + 2 H

There are other metals that can be used.

Does happen to a significant extent. The other bases work as well because of the lack of unpaired electrons.

On the other hand, there are many transi 2 HCl(aq) : H O(l) + CO.

They will do the job.

There are other carbonates and acids that can be used.

The farthest from the nucleus is D 2.

It has a small amount of product.

Edegcell is +0.619V with two half-filled subshells.

Under these conditions, Edeg for the couple must be > -0.041 V and produce one with half-filled and an empty Spontaneous.

+ 1.13 V. Fe(s) will do subshell.

2 Cu2+, SO, and H O(l) are included.

l is the wavelength of the light.

The blue light is caused by the disproportionation reaction. The blue light makes it easier to remove them.

The reflected light is yellow in this case.

The reflected light is white.

CuSO (g) + 2 H O(l) tate ion.

The BaCO is melting at room temperature.

Other metal carbonyls are liquids.

NiTi is the empirical formula.

45% is the extent of one unpaired electron.

There are feature problems.

There is a weak field ligand.

The graph has a negative slope of 2 C(s) + and are C/

3 H O should be yellow.

3Fe(H2O)64(NO3)2 should be green.

Impure Cu(s) containing SO.

A small and carefully controlled percentage of carbon is included. O are (c), (f) and (g). The answer is (b).

The answer is (d). The answer is yes.

The answer is (d).

The group 2 elements are OH Cd and Hg.

There are feature problems.

This complex ion has 2 H2O(l) in it.

Zinc forms a solu.

The constant is not large enough to be dissolved. The answer is (e).

The answer is yes.

The moderately insolu is dissolved by Pt ciently large. The answer is yes.

When 3Cl-4 is low, the AgCl(s) formed.

N ands around Pt.

O (NH ),,,,,,,,,,,,,,,,,,,,,,,,,,

The NH3 complex has a positive charge.

Light of certain wavelength OH charged. The light is colored.

The Mo complex is magnetic.

The isomerism in the thiocyanate ligand is shown by the negative cell potential. There is no complex that is diamagnetic.

Co(en)343+(aq) is a complex of nickel.

The co is blue.

2 OH-(aq) and 2 Zn are on the same side.

Ptcl 57 La + 6 C is occupied by Cu(H K+).

51 Sb + 2He : 123 53 I + 0n, 123 53 I + 52 Te.

Appendix G answers to practice examples and exercises. It took a similar amount of time to behave in that fashion. 13 dis/min is retained in the body for a long time.

C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

He will end up in the NaNO.

The minima of the other is 20Ca + 98.

29P should decay by emission.

The rate of formation should exceed 120I.

16 O is an example.

The quantity of is is taken into account by the rem. The answer is (b).

The answer is yes.

The rad is the dose. The answer is (d). The answer is (d).

He ated the matter.

Usually preferred is 1H + 1H.

The answer is (b). The answer is (d).

The answer is yes. The answer is yes.

It resides for a long time.

The answer is (b).

All of them have the same energy.

The solution will be decolorized.

It becomes carboxylic acid.

The C-H bonds are between the Enantiomers.

Carbon 2 is not straight. The energy of the Anti conformation is the lowest.

Carbon 2 is not straight.

There are no carbon atoms with the same name.

The group is attached to two carbons.

A disubstituted aromatic ring and Aldehyde, a more stable group.

There are two elements in C H O.

The compound 2 is easy to oxidize.

Carbons 2 and 4 are not straight.

Carbons 3 and 4 are not straight.

Cholesterol has eight different centers.

Double bond is Z.

The answer is (b).

The answer is yes.

N be butan-1-ol or butyraldehyde.

There is no response.

Increasing the concentration of n-butyl bro will double the rate.

The rate will go up.

The rate will go down.

The formation of nated is favored by the equilibrium.

The carbon skeleton of less steric hindrance is what happens when an organic compound undergoes a tion. A molecule is rearranged.

The attack on alkane is potential because of statistical factors.

The reactant molecule has six times as many 1o hydrogens and 2o hydrogens as E y.

The chain-lengths are formed in the reaction.

The one of the lowest priority is drawn in a clock. Reducing sugar has a suf.

The Cu O should be produced.

The formation of carbocation is involved in the N reaction.

S 2 reaction is a one-step reaction.

Trinolein is an oil.

There are salts of acids in soaps.

There is a suitable leaving group. Phos tions are unimolecular elimination reactions and E1 reac are derived from glycerols.

Proceed via carbocation intermediates.

The heads and tails of soaps andlipids are bimolecular.

Glycine " C double bonds in their hydrocarbon breaking and do not involve any of the other side of the equation.

The simplest a -amino acid is stearic acid.

The combination of two things.

There is less crowding. The acids are recommended in the diet of glycine.

The iso Table 28-2 has the highest electric point for safflower oil. The isoelectric point of glycine is a percentage.

Each molecule needs CH COO- to be denatured.

There are feature problems.

There are two of them that contain phosphate groups.

The Iodine number is 86.0.

The sugars value is 180. The Iodine number is 81.6.

In the case of DNA, proline will not migrate very effectively. ribose will migrate in the case of lysine.

A pyrimidine base is called aspartic sugar. The positively charged purine bases are adenine and guanine. One is not. The answer is (d).

In the case of is. The answer is (d).

The other pyrimidine base is called uracil. The answer is yes.

There is a sequence to AGC. The answer is (b). The answer is Ser-Ala-Ser, Ser-Lys-Ala, Ser-Ala-Lys.

The answer is (d). The answer is yes.

The answer is (d). The answer is (b).

All atoms of an element are 888-609- 888-609- 888-609- 888-609- 888-609- The empirical formula is C6H11O2. 1 mol CO2 forms for every mole C step used to solve a problem and whether or not the ratios remain valid, depending on the number of idea that atoms combine in simple numerical combustion. The exception is 1mol H2O for every 2mol H.

The atomic mass is 51.996 U.

The two-pan balance of the N2H4 mass is the same as that of the conclude two or more isotopes. The "mass" of naturally occurring Au atoms will appear less when mass 196.97g Au>NA is reached.

The product is called KCl(s).

1000 g is equivalent to 1470 cm3. The fraction tural formula is C4H6O2.

The structural formula of acetic acid in rect shows that no atoms can be created or destroyed with an instrument. COOH has the lowest value. There is a group of 1 in. The other four quantities mass were compared.

100 cm is 11 in.

This is now the largest mass because of the increase in the number of Cu atoms from 250.0 to 200.0 mL. It is to 1.000 M C12H22O11. The molecule is more than 1.5mol H2O 7 27 g, but the molarity of the first solution is reduced to 1/3, wrongly, that the tree interacted with its this is now the largest mass. The total amount of water. The final solution is 0.180 M KCl.

There are 4 NH31g2 + 5 O21g2 gas.

The atom has 4 NO1g2 and 6 H2O1l2.

If you don't know the atoms in the formula, you can use the molar and 1.2 mol H2O. We cannot mass by the mass fractions of the elements because of the mass of unreacted bromine. The answer shows the mass of magnesium bromide.

The following facts must be consistent.

230 g * 11 mol C>12.012 g2 11.98 mol C.

The idea that atoms are indivisible is not supported by the factor 0.90.

You can get 21.97 mol H and 3.995 mol H.

The increase in the forming 1mol C2H41g2 is the next line down.

C2H6 is the first line below 21g2 and has an ion concentration of 0.024 M.

The density data is based onclusive based T.

They conform to the ideal gas constant.

OF21R is uncertain. A wavelength of 2O1l2 is suitable for O21R.

It is possible for CaO and BaCO to be seen by the human eye. The explod wavelength is 91.2.

It is possible that BaSO41s2 is in an underground cavern. There would be no reaction to an isolated system.

An open system includes two reduction half-reactions and an acid with a base.

This can happen as seen.

The mass of hot water is twice that of the comet and Jupiter's surface.

There are particles in the agent. A solution is formed.

The greater momenta of the C/ T are the same if the wavelengths are the same.

The amount of heat length from either end of the box is greater than the amount of water required to cover the hump, beyond which the water is not present. Adding particle to those points is how this is done. Air pressure pushes measured amounts of reactants for a reaction up a partially evacuated pipe.

This is not open. The scale is the orbital. The temperature must have gone down after the change from 100 K to 200 K.

Arsenic is a compound.

The system's internal energy decreased.

The energy was transferred across the arrows in the same direction.

The balloon is warm in one direction.

The exothermic, q 6 0, has to be adjusted for the 0.667 L SO CHAPTER 9 21g2

The system has 98.0 kPa electron configuration of Si. The bottom leading to V is 0.743 L SO. The ten core electrons are 21g2.

The process is far from equilibrium and he is not affected by any other gases.

Zeff increases the amount of heat that can be removed.

The function of state is represented by the blue axis. When a process returns a false result.

The strong electron N atom pulls electron density away from the weight oils might become so mobile as to lose repulsions in an anion of high negative charge, creating a large dipole their lubricating properties. Intermolecular forces are stronger with F bonds oil.

The reason for the P/S comparison on moment is the same as the reason for the different elevation and expected trend.

The intermolecular attractions are smaller than the BH3 atoms due to the cation CH3 being in CCl4 and three pairs of London dispersion forces.

The first and last correspond to six electron pairs around a cen that give off heat to the surroundings.

We expect the compound AsF5.

Five bonds formed to H2O1g2.

Equal contributions from the be trigonal bipyramidal are involved. There are no formal charges if the Bragg equation is used.

The wavelength of the wave must be halved if there is a polyatomic ion and at least one atom with a formal tions. 1Bing 2 is required.

Four C60 mole ion are contained in the fcc unit cell. Two Lewis of the N atoms can be drawn, but they must retain a single pair of cules. There are four and eight structures in the unit cell. There are no formal charges for one structure.

One bond to H has a formal charge of sp2 and the formula is based on a unit cell. The formula is called K31C602.

The thermody 3CO2H is referred to as a resonance hybrid by the structure of CH and nonspontaneous.

The excited state of H nonspontaneous process will not occur with 2.

F2 should have a bond order of 1.

The observed is caused by the expansion of the gas in ference of one pair of electrons.

It is possible that the least satisfactory oils might solidify.

C/vapH and C/vapS have constant If and K.

The temperature is raised to 100 degC K by the values.

When 3 mol O2 is converted smaller of the two, the 3O + ] system is 326.4 kJ. The reverse is given as OH -. 2 mol O3 is the relevant equation.

NH2CH2NH21aq2 pK2 is 9.92.

The base ionized reactions are impossible with Kp.

Concentrations are based on mass.

The direction of net change must be in the C ward reaction.

Above the solution, 6H61l2 should follow PH(g) NH3 CH1 CH32COO- + H2O D.

A is xB and PA2 is xP.

+ A - PA2>P

According to the law, P decreased.

NH3CH1CH32COOH + OH- pKb is 11.37.

An inert gas has no effect.

If both components are on a constant-volume equilibrium condition, this will happen.

Composition of the equilibrium mixture will be determined by the vapor pressure of the solution.

The CO2 3 ion can act as a weak base, although it might be found at one pressure of H21g2 caused by forc CO2 3.

The sim is partly offset by the equilibrium 1.0 * 10-14/4.2 * 10-11. Two different solutions are shifting to the left. It's basic that equilibrium shifts in Na CO.

The chief has a higher yield of product.

CH3COO is 100 times larger.

chlorophenol is used to reform slopes.

Three atoms are joined by a single NaCl. It is a pair of unrelated acids.

The freezing point of the solution is Kw/[H3O+].

A concentrated solution of a weak acid may form a Lewis base. The final product has a lower pH than a dilute solution.

The expression K is used into the expression A. The bottle labeled Ka is labeled with the pH through the common-ion effect substitute and contains a more acidic solution. If K is less than 0.02, 10-5 has the acid with the somewhat stronger base than NH3.

A small amount is being added to the material balance.

AgCl2(s) + Cl-1aq2(s)

The overall solution will be absent because of the negative test for that ion. 2m is equivalent to 2.83 0.075 M NH31aq2.

log 2 is considered m log 2.

After starting at the same point, it will work.

The amount of strong acid remaining salt bridge is dependent on the plot. It would still produce a pH L 1. To preserve charge balance, this is the to Cu(s) and half-lives.

Bing 2 has a high pH and a gain in mass at the Cu(s) electrode second-order.

2 e exist. The reaction is similar to lence points. The curve would lose mass at the Zn(s) Figure 20-10).

The reaction is endothermic.

The condition cannot exist between the two points.

C/H is less than Ea for an exothermic.

There is no heat of reaction. In the case where Edeg 6 0, but in the dition cannot exist, this is the second most common occurrence.

The final solution is acidic, so right decrease until equilibrium is reached.

The concentrations are not the same. The solution would remain ment and increase the value of Ecell because of the mechanism that lowers the reaction barrier.

The increase in the rate of reaction caused by is doubled.

There are more collisions per unit time.

They can be assumed to be 0.041 V if Ecell is not found in tables. The potential is dependent on the chloride potential.

The immaterial is what AlF3 will have. The standard reduction potential for higher melting point is the only requirement. The Na+, K+, Rb+ AgNO31aq2 should be concentrated enough to bring a calomel electrode with a different chloride. Dry cells and lead-acid cells run atomic anions.

CaF2 will be affected by the high concentrations of reactants and ion. The formation of F- is derived from the products eventually reach their equilibrium polarizing power, and so it will undergo hydroly ues, where C/rG and Ecell both become 0.

An entirely plausible Ni and Cu are less active than MNO21s2 + Bing 2 O21g2 1M.

N21g2 + 3 H21g2 2 NH31g2 is a solution that compares the rate of disappearance of N geometry around the Be atom. There was a disappearance of H linear to trigonal.

There is a possibility that the Mg(s) is oxi 3 is twice as much as the Ag(s) is less than in pure water great. If the initial and instantaneous dized to CO21g2 is reduced because of the common-ion effect.

The concentration 2 MgO1s2 + C1s2 becomes so throughout a reaction.

A95 is heating the group 2 carbonates. The equation species suggest that the central O atom is sp2 electricity and that the Lewis structures do not conduct the oxide.

O3 was hybridized in O 3.

The first two are easy to do with the Mg2+ ion.

Presumably, when it's satisfactory for describing the bonding six-coordinate complex.

Three N atoms can give an electron large enough to fix the N3- anion.

Bing 2 N21g2 is called pies an antibonding orbital.

The oxygen-oxygen bonds in O3 are slightly different.

The termi shows more positive character in CH32, which leads to all four Cl- ligands in the same plane. The same isomer can't be obtained by compound and forms, which is why AlF3 is an electron deficient.

The Cl atom is smaller than the br atom.

2 in equation 21.29 by 1mol CO in Br atoms does so in a single step, while ion.

110.5 kJ>mol CO1g2 four Cl atoms are in the PCl4 steps.

The emissions and electron can be eliminated by removing one O2 between the ends.

The element is the same after 12 solutions, followed by chemical or elec g rays.

The trolytic reduction to the metal is provided by 3 Be2+. There are 12 units of positive charge for Francium.

The backbone can be maintained with little or no more than two additional O.

The significant period of time at a high activity is CHAPTER 22 O. S.

Refer to Table 25.2 and Figure 25-7 and polyphosphate focus on magic numbers and the relative thick and F, compared to Xe and Cl, makes XeF2 a. The neutral molecule is the sum of the O.S.

A stable nuclide is 21g2 at the [Cd5]3. Cu falls below the Pt anode, and NaI yields I2 at the anode dal.

Attaching to either butan-2-ol will produce OH.

Attaching to one of the will attacks from below the ring is superimposable.

"pentyl alcohol" is not adequate.

The preferred name is pentan-2-ol.

The name 2-pentanol is often used.

The series can only be limited to straight-chain alkanes with unsaturation. A dialdehyde has two p as a terminal atom.

A H ClC radical can be formed by reacting with a Cl polar protic and stabilizing a carbocation.

The SN1 mechanism is responsible for forming cl ether.

L-1 - 2-glucose is the conformer with the methyl group. The position has higher energy and no D-1-2-glucose. If burned, this polypeptide would release more energy.

The net position is at the C-terminal amino acid, where the larger group, - CH3, is located.

There are four stereoisomers attached to the 2-bromo-3 formation.

OH groups could have the two Br atoms on opposite sides of the obtained because hydration proceeds through hydrogen bonds between molecule and its mirror image, making a total carbocation. The carbocation can be attacked randomly, but not in the stereoisomers.

The online chapter, Chapter 28 is indicated by the letters preceding a page reference.

1046-1049 oxygen is used in the Henderson-Hasselbalch equation.

Concentration change reactions are expressed as ruff degradation.

The gases are noble.

The atomic mass is relative to carbon-12.

The numbering of groups is explained on page 52. The metals are and the nonmetals are not.

The International Union of Pure and Applied Chemistry endorsed the version on May 1. Atomic mass are from Pure Appl. They are given five figures. The IUPAC announced the verification of the discoveries on December 30, 2015. The symbols of these elements are expected to take several months to complete.

The mass numbers of the most stable radioactive elements are listed.

1 joule 1J2 is equal to 1 N m.

PNIPAM was the first temperature-responsive polymer.

A PNIPAM hydrogel has a unique property that makes it transition from a hydrated state to a dehydrated state. The temperature is 32 degrees.

Instructors can maximize class time with a variety of assessments that are easy to assign and personalize to their students' learning styles. The assessments help students get ready for class. The gradebook gives insight into student and class performance before the first test. Instructors can spend class time where students need it the most.

  • 1. Matter: Its Properties and Measurement 1-1. The Scientific Method 1-2. Properties of Matter 1-3. Classification of Matter 1-4. Measurement of Matter: SI (Metric) Units 1-5. Density and Percent Composition: Their Use in Problem Solving 1-6. Uncertainties in Scientific Measurements 1-7. Significant Figures Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 2. Atoms and the Atomic Theory 2-1. Early Chemical Discoveries and the Atomic Theory 2-2. Electrons and Other Discoveries in Atomic Physics 2-3. The Nuclear Atom 2-4. Chemical Elements 2-5. Atomic Mass 2-6. Introduction to the Periodic Table 2-7. The Concept of the Mole and the Avogadro Constant 2-8. Using the Mole Concept in Calculations Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 3. Chemical Compounds 3-1. Types of Chemical Compounds and Their Formulas 3-2. The Mole Concept and Chemical Compounds 3-3. Composition of Chemical Compounds 3-4. Oxidation States: A Useful Tool in Describing Chemical Compounds 3-5. Naming Compounds: Organic and Inorganic Compounds 3-6. Names and Formulas of Inorganic Compounds 3-7. Names and Formulas of Organic Compounds Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 4. Chemical Reactions 4-1. Chemical Reactions and Chemical Equations 4-2. Chemical Equations and Stoichiometry 4-3. Chemical Reactions in Solution 4-4. Determining the Limiting Reactant 4-5. Other Practical Matters in Reaction Stoichiometry 4-6. The Extent of Reaction Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 5. Introduction to Reactions in Aqueous Solutions 5-1. The Nature of Aqueous Solutions 5-2. Precipitation Reactions 5-3. Acid-Base Reactions 5-4. Oxidation-Reduction Reactions: Some General Principles 5-5. Balancing Oxidation-Reduction Equations 5-6. Oxidizing and Reducing Agents 5-7. Stoichiometry of Reactions in Aqueous Solutions: Titrations Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 6. Gases 6-1. Properties of Gases: Gas Pressure 6-2. The Simple Gas Laws 6-3. Combining the Gas Laws: The Ideal Gas Equation and the General Gas Equation 6-4. Applications of the Ideal Gas Equation 6-5. Gases in Chemical Reactions 6-6. Mixtures of Gases 6-7. Kinetic-Molecular Theory of Gases 6-8. Gas Properties Relating to the Kinetic-Molecular Theory 6-9. Nonideal (Real) Gases Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 7. Thermochemistry 7-1. Getting Started: Some Terminology 7-2. Heat 7-3. Heats of Reaction and Calorimetry 7-4. Work 7-5. The First Law of Thermodynamics 7-6. Application of the First Law to Chemical and Physical Changes 7-7. Indirect Determination of rH: Hess's Law 7-8. Standard Enthalpies of Formation 7-9. Fuels as Sources of Energy 7-10. Spontaneous and Nonspontaneous Processes: An Introduction Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 8. Electrons in Atoms 8-1. Electromagnetic Radiation 8-2. Prelude to Quantum Theory 8-3. Energy Levels, Spectrum, and Ionization Energy of the Hydrogen Atom 8-4. Two Ideas Leading to Quantum Mechanics 8-5. Wave Mechanics 8-6. Quantum Theory of the Hydrogen Atom 8-7. Interpreting and Representing the Orbitals of the Hydrogen Atom 8-8. Electron Spin: A Fourth Quantum Number 8-9. Multielectron Atoms 8-10. Electron Configurations 8-11. Electron Configurations and the Periodic Table Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 9. The Periodic Table and Some Atomic Properties 9-1. Classifying the Elements: The Periodic Law and the Periodic Table 9-2. Metals and Nonmetals and Their Ions 9-3. Sizes of Atoms and Ions 9-4. Ionization Energy 9-5. Electron Affinity 9-6. Magnetic Properties 9-7. Polarizability Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 10. Chemical Bonding I: Basic Concepts 10-1. Lewis Theory: An Overview 10-2. Covalent Bonding: An Introduction 10-3. Polar Covalent Bonds and Electrostatic Potential Maps 10-4. Writing Lewis Structures 10-5. Resonance 10-6. Exceptions to the Octet Rule 10-7. Shapes of Molecules 10-8. Bond Order and Bond Lengths 10-9. Bond Energies Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 11. Chemical Bonding II: Valence Bond and Molecular Orbital Theories 11-1. What a Bonding Theory Should Do 11-2. Introduction to the Valence Bond Method 11-3. Hybridization of Atomic Orbitals 11-4. Multiple Covalent Bonds 11-5. Molecular Orbital Theory 11-6. Delocalized Electrons: An Explanation Based on Molecular Orbital Theory 11-7. Some Unresolved Issues: Can Electron Density Plots Help? Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 12. Intermolecular Forces: Liquids and Solids 12-1. Intermolecular Forces 12-2. Some Properties of Liquids 12-3. Some Properties of Solids 12-4. Phase Diagrams 12-5. The Nature of Bonding in Solids 12-6. Crystal Structures 12-7. Energy Changes in the Formation of Ionic Crystals Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 13. Spontaneous Change: Entropy and Gibbs Energy 13-1. Entropy: Boltzmann's View 13-2. Entropy Change: Clausius's View 13-3. Combining Boltzmann's and Clausius's Ideas: Absolute Entropies 13-4. Criterion for Spontaneous Change: The Second Law of Thermodynamics 13-5. Gibbs Energy Change of a System of Variable Composition <=rGdeg <=rG 13-6. <=rGdeg and K as Functions of Temperature 13-7. Coupled Reactions 13-8. Chemical Potential and Thermodynamics of Spontaneous Chemical Change Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 14. Solutions and Their Physical Properties 14-1. Types of Solutions: Some Terminology 14-2. Solution Concentration 14-3. Intermolecular Forces and the Solution Process 14-4. Solution Formation and Equilibrium 14-5. Solubilities of Gases 14-6. Vapor Pressures of Solutions 14-7. Osmotic Pressure 14-8. Freezing-Point Depression and Boiling-Point Elevation of Nonelectrolyte Solutions 14-9. Solutions of Electrolytes 14-10. Colloidal Mixtures Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 15. Principles of Chemical Equilibrium 15-1. The Nature of the Equilibrium State 15-2. The Equilibrium Constant Expression 15-3. Relationships Involving Equilibrium Constants 15-4. The Magnitude of an Equilibrium Constant 15-5. Predicting the Direction of Net Chemical Change 15-6. Altering Equilibrium Conditions: Le Chatelier's Principle 15-7. Equilibrium Calculations: Some Illustrative Examples Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 16. Acids and Bases 16-1. Acids, Bases, and Conjugate Acid-Base Pairs 16-2. Self-Ionization of Water and the pH Scale 16-3. Ionization of Acids and Bases in Water 16-4. Strong Acids and Strong Bases 16-5. Weak Acids and Weak Bases 16-6. Polyprotic Acids 16-7. Simultaneous or Consecutive Acid-Base Reactions: A General Approach 16-8. Ions as Acids and Bases 16-9. Qualitative Aspects of Acid-Base Reactions 16-10. Molecular Structure and Acid-Base Behavior 16-11. Lewis Acids and Bases Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 17. Additional Aspects of Acid-Base Equilibria 17-1. Common-Ion Effect in Acid-Base Equilibria 17-2. Buffer Solutions 17-3. Acid-Base Indicators 17-4. Neutralization Reactions and Titration Curves 17-5. Solutions of Salts of Polyprotic Acids 17-6. Acid-Base Equilibrium Calculations: A Summary Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 18. Solubility and Complex-Ion Equilibria 18-1. Solubility Product Constant, Ksp 18-2. Relationship Between Solubility and Ksp 18-3. Common-Ion Effect in Solubility Equilibria 18-4. Limitations of the Ksp Concept 18-5. Criteria for Precipitation and Its Completeness 18-6. Fractional Precipitation 18-7. Solubility and pH 18-8. Equilibria Involving Complex Ions 18-9. Qualitative Cation Analysis Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 19. Electrochemistry 19-1. Electrode Potentials and Their Measurement 19-2. Standard Electrode Potentials 19-3. Ecell, <=rGdeg and K 19-4.Ecell as a Function of Concentrations 19-5. Batteries: Producing Electricity Through Chemical Reactions 19-6. Corrosion: Unwanted Voltaic Cells 19-7. Electrolysis: Causing Nonspontaneous Reactions to Occur 19-8. Industrial Electrolysis Processes Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 20. Chemical Kinetics 20-1. Rate of a Chemical Reaction 20-2. Measuring Reaction Rates 20-3. Effect of Concentration on Reaction Rates: The Rate Law 20-4. Zero-Order Reactions 20-5. First-Order Reactions 20-6. Second-Order Reactions 20-7. Reaction Kinetics: A Summary 20-8. Theoretical Models for Chemical Kinetics 20-9. The Effect of Temperature on Reaction Rates 20-10. Reaction Mechanisms 20-11. Catalysis Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 21. Chemistry of the Main-Group Elements I: Groups 1, 2, 13, and 14 21-1. Periodic Trends and Charge Density 21-2. Group 1: The Alkali Metals 21-3. Group 2: The Alkaline Earth Metals 21-4. Group 13: The Boron Family 21-5. Group 14: The Carbon Family Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 22. Chemistry of the Main-Group Elements II: Groups 18, 17, 16, 15, and Hydrogen 22-1. Periodic Trends in Bonding 22-2. Group 18: The Noble Gases 22-3. Group 17: The Halogens 22-4. Group 16: The Oxygen Family 22-5. Group 15: The Nitrogen Family 22-6. Hydrogen: A Unique Element Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 23. The Transition Elements 23-1. General Properties 23-2. Principles of Extractive Metallurgy 23-3. Metallurgy of Iron and Steel 23-4. First-Row Transition Metal Elements: Scandium to Manganese 23-5. The Iron Triad: Iron, Cobalt, and Nickel 23-6. Group 11: Copper, Silver, and Gold 23-7. Group 12: Zinc, Cadmium, and Mercury 23-8. Lanthanides 23-9. High-Temperature Superconductors Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 24. Complex Ions and Coordination Compounds 24-1. Werner's Theory of Coordination Compounds: An Overview 24-2. Ligands 24-3. Nomenclature 24-4. Isomerism 24-5. Bonding in Complex Ions: Crystal Field Theory 24-6. Magnetic Properties of Coordination Compounds and Crystal Field Theory 24-7. Color and the Colors of Complexes 24-8. Aspects of Complex-Ion Equilibria 24-9. Acid-Base Reactions of Complex Ions 24-10. Some Kinetic Considerations 24-11. Applications of Coordination Chemistry Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 25. Nuclear Chemistry 25-1. Radioactivity 25-2. Naturally Occurring Radioactive Isotopes 25-3. Nuclear Reactions and Artificially Induced Radioactivity 25-4. Transuranium Elements 25-5. Rate of Radioactive Decay 25-6. Energetics of Nuclear Reactions 25-7. Nuclear Stability 25-8. Nuclear Fission 25-9. Nuclear Fusion 25-10. Effect of Radiation on Matter 25-11. Applications of Radioisotopes Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problems Self-Assessment Exercises
  • 26. Structures of Organic Compounds 26-1. Organic Compounds and Structures: An Overview 26-2. Alkanes 26-3. Cycloalkanes 26-4. Stereoisomerism in Organic Compounds 26-5. Alkenes and Alkynes 26-6. Aromatic Hydrocarbons 26-7. Organic Compounds Containing Functional Groups 26-8. From Molecular Formula to Molecular Structure Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problem Self-Assessment Exercises
  • 27. Reactions of Organic Compounds 27-1. Organic Reactions: An Introduction 27-2. Introduction to Nucleophilic Substitution Reactions 27-3. Introduction to Elimination Reactions 27-4. Reactions of Alcohols 27-5. Introduction to Addition Reactions: Reactions of Alkenes 27-6. Electrophilic Aromatic Substitution 27-7. Reactions of Alkanes 27-8. Polymers and Polymerization Reactions 27-9. Synthesis of Organic Compounds Summary Integrative Example Exercises Integrative and Advanced Exercises Feature Problem Self-Assessment Exercises
  • 28. Chemistry of the Living State on MasteringChemistry on (www.masteringchemistry.com)
  • Appendix A. Mathematical Operations
  • Appendix B. Some Basic Physical Concepts
  • Appendix C. SI Units
  • Appendix D. Data Tables
  • Appendix E. Concept Maps
  • Appendix F. Glossary
  • Appendix G. Answers to Practice Examples and Selected Exercises
  • Appendix H. Answers to Concept Assessment Questions
  • Index
  • Back Cover